Colorimetric Test Kit for Cu2+ Detection

被引:227
作者
Sheng, Ruilong [1 ]
Wang, Pengfei [1 ]
Gao, Yunhua [1 ]
Wu, Yan [1 ]
Liu, Weimin [1 ]
Ma, Jingjin [1 ]
Li, Huaping [2 ,3 ,4 ]
Wu, Shikang [1 ]
机构
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Lab Organ Optoelect Funct Mat & Mol Engn, Beijing 100190, Peoples R China
[2] Univ Calif Santa Barbara, Ctr Polymers & Organ Solids, Dept Mat, Santa Barbara, CA 93106 USA
[3] Univ Calif Santa Barbara, Ctr Polymers & Organ Solids, Dept Chem, Santa Barbara, CA 93106 USA
[4] Univ Calif Santa Barbara, Ctr Polymers & Organ Solids, Dept Biochem, Santa Barbara, CA 93106 USA
关键词
D O I
10.1021/ol802117p
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A coumarin-based colorimetric chemosensor 1 was designed and synthesized. It exhibits good sensitivity and selectivity for the copper cation over other cations such as Zn2+, Cd2+, Pb2+, Co2+, Fe2+, Ni2+, Ag+, and alkali and alkaline earth metal cations both in aqueous solution and on paper-made test kits. The change in color is very easily observed by the naked eye in the presence of Cu2+. cation, whereas other metal cations do not induce such a change. The quantitative detection of Cu2+ was preliminarily examined.
引用
收藏
页码:5015 / 5018
页数:4
相关论文
共 41 条
[1]   Neurodegenerative diseases and oxidative stress [J].
Barnham, KJ ;
Masters, CL ;
Bush, AI .
NATURE REVIEWS DRUG DISCOVERY, 2004, 3 (03) :205-214
[2]   Biological inorganic and bioinorganic chemistry of neurodegeneration based on prion and Alzheimer diseases [J].
Brown, DR ;
Kozlowski, H .
DALTON TRANSACTIONS, 2004, (13) :1907-1917
[3]   ICCC34 - golden edition of coordination chemistry reviews. Coordination chemistry for the neurosciences [J].
Burdette, SC ;
Lippard, SJ .
COORDINATION CHEMISTRY REVIEWS, 2001, 216 :333-361
[4]   Synthesis, crystal structure, and magnetic properties of tetraphenylarsonium tetrachloro(oxalato)rhenate(IV) and bis (2,2′-bipyridine)tetrachloro(μ-oxalato)copper(II)rhenium(IV) [J].
Chiozzone, R ;
González, R ;
Kremer, C ;
De Munno, G ;
Cano, J ;
Lloret, F ;
Julve, M ;
Faus, J .
INORGANIC CHEMISTRY, 1999, 38 (21) :4745-4752
[5]   A new reverse PET chemosensor and its chelatoselective aromatic cadmiation [J].
Choi, M ;
Kim, M ;
Lee, KD ;
Han, KN ;
Yoon, IA ;
Chung, HJ ;
Yoon, J .
ORGANIC LETTERS, 2001, 3 (22) :3455-3457
[6]   Signaling recognition events with fluorescent sensors and switches [J].
de Silva, AP ;
Gunaratne, HQN ;
Gunnlaugsson, T ;
Huxley, AJM ;
McCoy, CP ;
Rademacher, JT ;
Rice, TE .
CHEMICAL REVIEWS, 1997, 97 (05) :1515-1566
[7]   A long-wavelength fluorescent chemodosimeter selective for Cu(II) ion in water [J].
Dujols, V ;
Ford, F ;
Czarnik, AW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (31) :7386-7387
[8]   A monostyryl-boradiazaindacene (BODIPY) derivative as colorimetric and fluorescent probe for cyanide ions [J].
Ekmekci, Zeynep ;
Yilmaz, M. Deniz ;
Akkaya, Engin U. .
ORGANIC LETTERS, 2008, 10 (03) :461-464
[9]   Detection of amines and unprotected amino acids in aqueous conditions by formation of highly fluorescent iminium ions [J].
Feuster, EK ;
Glass, TE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (52) :16174-16175
[10]   Copper homeostasis and neurodegenerative disorders (Alzheimer's, prion, and Parkinson's diseases and amyotrophic lateral sclerosis) [J].
Gaggelli, Elena ;
Kozlowski, Henryk ;
Valensin, Daniela ;
Valensin, Gianni .
CHEMICAL REVIEWS, 2006, 106 (06) :1995-2044