Triphenylphosphine-supported synthesis of two-dimensional silver(I) complex with (1,3,4-thiadiazole-2,5-diyldithio)diacetic acid

被引：0

作者：

Subri, Noor H. A. ^{[1
]}

Haziz, Umie F. M. ^{[1
]}

Razali, Mohd. R. ^{[1
]}

机构：

[1] Univ Sains Malaysia, Sch Chem Sci, Minden 11800, Penang, Malaysia

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2017年 / 192卷 / 03期

关键词：

1,3,4-Thiadiazole; photoluminescence; silver(I) complex; 2D-net; COORDINATION POLYMERS; HYDROTHERMAL SYNTHESES; MAGNETIC-PROPERTIES; PHOTOLUMINESCENCE; FRAMEWORKS; LIGANDS;

D O I：

10.1080/10426507.2016.1236105

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of dicarboxylate ligand, (1,3,4-thiadiazole-2,5-diyldithio)diacetic acid (H(2)tdza) with silver(I) acetate and triphenylphosphine (PPh3) facilitate the formation of complex [Ag-2(tdza)(PPh3)(2)](n)(1). The complex was characterized by elemental analysis, FT-IR spectroscopy, H-1-NMR, C-13-NMR and P-31-NMR spectroscopy, and single crystal X-ray diffraction. Structural analysis revealed that complex 1 has a 2D topologically promising architecture as a result from the formation of 26-membered cyclic ring. The tdza2(-) ligand in 1 displays unprecedented mu(4)-bridging mode which is also the first example for this ligand. The interdigitating arrangement and - stacking between 2D arrays stabilized the formation of complex 1.

引用

页码：271 / 275

页数：5

共 31 条

[1]

[Anonymous], 2005, APEXII

[2] Anti-proliferative and anti-tumor activity of silver(I) compounds [J].

Banti, Christina N. ;

Hadjikakou, Sotiris K. .

METALLOMICS, 2013, 5 (06) :569-596

[3]

Barbour L.J., 2001, J SUPRAMOL CHEM, V1, P189, DOI [DOI 10.1016/S1472-7862(02)00030-8, 10.1016/S1472-7862(02)00030-8]

[4] Coordination polymers, metal-organic frameworks and the need for terminology guidelines [J].

Batten, Stuart R. ;

Champness, Neil R. ;

Chen, Xiao-Ming ;

Garcia-Martinez, Javier ;

Kitagawa, Susumu ;

Ohrstrom, Lars ;

O'Keeffe, Michael ;

Suh, Myunghyun Paik ;

Reedijk, Jan .

CRYSTENGCOMM, 2012, 14 (09) :3001-3004

[5] Ring, polymer and network structures in silver(I) complexes with dipyridyl and diphosphine ligands [J].

Brandys, MC ;

Puddephatt, RJ .

CHEMICAL COMMUNICATIONS, 2001, (16) :1508-1509

[6] Efficient aziridination of olefins catalyzed by a unique disilver(I) compound [J].

Cui, Y ;

He, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (52) :16202-16203

[7] Bis(2,2′-bipyridine-κN,N′){[5-(carboxymethylsulfanyl)-1,3,4-thiadiazol-2-ylsulfanyl]acetato-κO}copper(II) [5-(carboxymethylsulfanyl)-1,3,4-thiadiazol-2-ylsulfanyl]acetate dihydrate [J].

Gao, S ;

Huo, LH ;

Zhao, H ;

Ng, SW .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 :M126-M128

[8] The Cambridge Structural Database [J].

Groom, Colin R. ;

Bruno, Ian J. ;

Lightfoot, Matthew P. ;

Ward, Suzanna C. .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2016, 72 :171-179

[9] INFINITE POLYMERIC FRAMEWORKS CONSISTING OF 3 DIMENSIONALLY LINKED ROD-LIKE SEGMENTS [J].

HOSKINS, BF ;

ROBSON, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (15) :5962-5964

[10] A critical account on π-π stacking in metal complexes with aromatic nitrogen-containing ligands [J].

Janiak, C .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (21) :3885-3896

← 1 2 3 4 →