Surface-mounted MOF templated fabrication of homochiral polymer thin film for enantioselective adsorption of drugs

被引：39

作者：

Gu, Zhi-Gang ^{[1
]}

Fu, Wen-Qiang ^{[1
]}

Liu, Min ^{[1
]}

Zhang, Jian ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 09期

关键词：

METAL-ORGANIC FRAMEWORKS; SEPARATION; CHEMISTRY; GAS; RESOLUTION; CATALYSIS; COATINGS; LIQUID;

D O I：

10.1039/c6cc08342k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A self-polymerized chiral monomer 3,4-dihydroxy-L-phenylalanine (L-DOPA) has been introduced into the pores of an achiral surface-mounted metal organic framework (SURMOF), and then the homochiral poly(L-DOPA) thin film has been successfully formed after UV light irradiation and etching of the SURMOF. Remarkably, such a poly(L-DOPA) thin film exhibited enantioselective adsorption of naproxen. This study opened a SURMOF-templated approach for preparing porous polymer thin films.

引用

页码：1470 / 1473

页数：4

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