MICROWAVE ABSORPTIVE BEHAVIOR OF NANOCRYSTALLINE Ba3Co1.3Zn0.3Cu0.4Fe24O41 POWDER

被引:0
作者
Caffarena, V. R. [1 ]
Ogasawara, T. [2 ]
Capitaneo, J. L. [3 ]
Pinho, M. Silveira [4 ]
机构
[1] Petr Brasileiro SA Gas&Power, BR-20031004 Rio De Janeiro, Brazil
[2] UFRJ, COPPE, PEMM, Dept Met & Mat Engn,Ilha Fundao, BR-21945970 Rio De Janeiro, Brazil
[3] Ilha Fundao, Inst Macromol Prof Eloisa Mano, BR-21945970 Rio De Janeiro, Brazil
[4] IPqM, Brazilian Navy Res Inst, BR-21931090 Rio De Janeiro, Brazil
关键词
Z-type hexaferrite; RAM; magnetic properties; sol-gel synthesis;
D O I
暂无
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In the present work, Cu2+ and Zn2+ ions were incorporated into the structure of Ba3Co2Fe24O41, in order to obtain the Ba3Co1.3Zn0.3Cu0.4Fe24O41 structure, by the sol-gel precursor method in N-2 inert atmosphere. The magnetization curves of Ba3Co1.3Zn0.3Cu0.4Fe24O41 hexaferrite nanopowders were analyzed as a function of temperature, to evaluate the superparamagnetic (SPM) behavior and its effect on the microwave absorption measurements. The permittivity (epsilon) and permeability (mu) values were obtained by using the transmission/reflection (T/R) method in a waveguide to evaluate the microwave absorption properties at S and X-Ku bands, for radar absorber material (RAM) application. The partial substitution of Co for Zn and Cu ions and the superparamagnetic contribution improved the ceramics' magnetic permeability, resulting in a microwave absorption greater than 90.0% (reflectivity <= -10 dB) at 10.0-12.5 GHz and 13.0-16.0 GHz, with 2.5 and 2.0 mm thick, respectively.
引用
收藏
页码:235 / 239
页数:5
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