The Synthesis of η-1,2,3,4,5,6-Hexafluorocyclohexane (Benzene Hexafluoride) from Benzene

被引：15

作者：

Durie, Alastair J. ^{[1
]}

Slawin, Alexandra M. Z. ^{[1
]}

Lebl, Tomas ^{[1
]}

O'Hagan, David ^{[1
]}

机构：

[1] Univ St Andrews, EaStChem Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 40期

基金：

英国工程与自然科学研究理事会;

关键词：

benzene hexafluoride; conformational analysis; hexafluorocyclohexane; organofluorine chemistry; FLUORINE; SULFATES; COMPLEX; BONDS;

D O I：

10.1002/anie.201205577

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Six of the best: Benzene had been used by Faraday and Mitscherlich in their respective synthesis of hexachloro- and hexabromocyclohexane in the early 19th century. Also starting from benzene, Î·-1,2,3,4,5,6- hexafluorocyclohexane (benzene hexafluoride; see X-ray structure of a dimer) was now synthesized in five steps. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10086 / 10088

页数：3

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