Preparation and Catalysis of Carbon-Supported Iron Catalysts for Fischer-Tropsch Synthesis

被引：108
作者：
Sun, Bo [1 ,2 ]
Xu, Ke [1 ,2 ]
Luan Nguyen [3 ]
Qiao, Minghua [1 ,2 ]
Tao, Franklin [3 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[2] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
[3] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA
来源：
CHEMCATCHEM | 2012年 / 4卷 / 10期
关键词：
iron; carbon materials; Fischer-Tropsch; heterogeneous catalysis; water-gas shift; CHEMICAL-VAPOR-DEPOSITION; ACTIVATED-CARBON; CO HYDROGENATION; COBALT CATALYSTS; GLASSY-CARBON; HYDROTHERMAL CARBONIZATION; MOSSBAUER-SPECTROSCOPY; TRANSPORTATION FUELS; METAL NANOPARTICLES; CRYSTALLITE SIZE;
D O I：
10.1002/cctc.201200241
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
FischerTropsch synthesis (FTS) is essential for the transformation of natural gas, coal, and biomass to clean transportation fuels and value-added chemicals. Traditionally, iron catalysts for FTS are predominantly fused iron catalysts and precipitated iron catalysts using silica as the support. Owing to an intense surge in interest in carbon materials during recent years, along with the unique properties of these materials, such as high surface area, high porosity, and ample structures, carbon-supported iron-based FTS catalysts have attracted increasing attention. In this detailed review of the progress of the Fe/C catalysts for FTS in the last three decades, particular emphasis is put on their preparation, characterization, and catalytic performance relevant to the characteristics of carbon materials. This review is intended to be a valuable resource to researchers interested in this exciting field of catalysis, as well as the foundation for those investigating applications of novel carbon materials. A brief discussion is also devoted to the challenges and opportunities regarding the future development of Fe/C FTS catalysts.
引用
收藏
页码：1498 / 1511
页数：14
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