Linear sweep voltammetry at the tubular electrode: Theory of EC mechanisms

被引：5

作者：

Thompson, M ^{[1
]}

Compton, RG ^{[1
]}

机构：

[1] Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2006年 / 587卷 / 02期

关键词：

tubular electrode; linear sweep voltammetry; EC mechanism; computational electrochemistry;

D O I：

10.1016/j.jelechem.2005.11.007

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The concentration profile of a species generated electrochemically in a tubular flowing electrode is obtained via numerical simulation for the case of an EC mechanism, where the species formed at the electrode is subsequently lost through a homogeneous first order decay process. Voltammetric waves are simulated and the variation of the half-wave potential as a function of the first order rate constant and the normalised variables of the mass transport equation is explored. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：186 / 192

页数：7

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