Synthesis and structure of pseudo-three dimensional hybrid iodobismuthate semiconductors

被引：33

作者：

Dennington, Adam J. ^{[1
]}

Weller, Mark T. ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Claverton Down, England

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 44期

基金：

英国工程与自然科学研究理事会;

关键词：

ORGANIC-INORGANIC PEROVSKITES; OPTICAL-PROPERTIES; CRYSTAL-STRUCTURE; POLYNUCLEAR; COMPLEXES; EMERGENCE; CATIONS; CHAINS; TIN;

D O I：

10.1039/c6dt03602c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, structures and semiconducting properties of three isostructural, piperazinium-cation based iodobismuthates, [NH2(CH2)(4)NH2][BiI4](2)center dot 4H(2)O, [CH3NH(CH2)(4)NH2][BiI4](2)center dot 3H(2)O and [CH3NH(CH2)(4) HNCH3][BiI4](2)center dot 2H(2)O, are reported. The materials have pseudo-three dimensional structures consisting of infinite chains formed from edge/face sharing [BiI6] octahedra with short interchain I...I interactions of <3.8 angstrom. The materials have band gaps of similar to 1.9-2.0 eV and show variable optoelectronic properties based on the degree of methylation of the templating piperazinium ring-based organic species and the accordingly associated level of solvation in the structure.

引用

页码：17974 / 17979

页数：6

共 43 条

[1] Trinuclear iodobismuthate complex [Na3(Me2CO)12][Bi3I12]: Synthesis and crystal structure [J].

Adonin, S. A. ;

Peresypkina, E. V. ;

Sokolov, M. N. ;

Fedin, V. P. .

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2014, 40 (12) :867-870

[2] Polynuclear halide complexes of Bi(III): From structural diversity to the new properties [J].

Adonin, Sergey A. ;

Sokolov, Maxim N. ;

Fedin, Vladimir P. .

COORDINATION CHEMISTRY REVIEWS, 2016, 312 :1-21

[3] Reversible dynamic isomerism change in the solid state, from Bi4I16 clusters to BiI4 1D chains in L-cystine based hybrids: templating effect of cations in iodobismuthate network formation [J].

Bi, Wenhua ;

Mercier, Nicolas .

CHEMICAL COMMUNICATIONS, 2008, (44) :5743-5745

[4] Identifying defect-tolerant semiconductors with high minority-carrier lifetimes: beyond hybrid lead halide perovskites [J].

Brandt, Riley E. ;

Stevanovic, Vladan ;

Ginley, David S. ;

Buonassisi, Tonio .

MRS COMMUNICATIONS, 2015, 5 (02) :265-275

[5]

Chaabouni S, 1997, J CHEM CRYSTALLOGR, V27, P527

[6] A Water Sensitive Hydrate: The Bis-Catena Complex Salt [Mn(H2O)6][BiI4]2•2H2O [J].

Erbe, Manuela ;

Koehler, Daniel ;

Ruck, Michael .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (08) :1513-1515

[7] Preparation and crystal structure of [Bi3I(C4H8O3H2)2(C4H8O3H)5]2-Bi8I30 containing the novel polynuclear [Bi8I30]6- anion [J].

Feldmann, C .

JOURNAL OF SOLID STATE CHEMISTRY, 2003, 172 (01) :53-58

[8] Band Gaps of the Lead-Free Halide Double Perovskites Cs2BiAgCl6 and Cs2BiAgBr6 from Theory and Experiment [J].

Filip, Marina R. ;

Hillman, Samuel ;

Haghighirad, Amir Abbas ;

Snaith, Henry J. ;

Giustino, Feliciano .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2016, 7 (13) :2579-2585

[9] Periodic and incommensurately modulated phases in a (2-methylimidazolium) tetraiodobismuthate(III) thermochromic organic-inorganic hybrid [J].

Gagor, A. ;

Weclawik, M. ;

Bondzior, B. ;

Jakubas, R. .

CRYSTENGCOMM, 2015, 17 (17) :3286-3296

[10] (CH3NH3)2Pb(SCN)2I2: A More Stable Structural Motif for Hybrid Halide Photovoltaics? [J].

Ganose, Alex M. ;

Savory, Christopher N. ;

Scanlon, David O. .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2015, 6 (22) :4594-4598

← 1 2 3 4 5 →