Advances in the Production and Chemistry of the Heaviest Elements

被引:179
|
作者
Tuerler, Andreas [1 ,2 ]
Pershina, Valeria [3 ]
机构
[1] Univ Bern, Lab Radiochem & Environm Chem, Dept Chem & Biochem, CH-3012 Bern, Switzerland
[2] Paul Scherrer Inst, Lab Radiochem & Environm Chem, Dept Biol & Chem, CH-5232 Villigen, Switzerland
[3] GSI Helmholtzzentrum Schwerionenforsch GmbH, D-64291 Darmstadt, Germany
基金
瑞士国家科学基金会;
关键词
DENSITY-FUNCTIONAL THEORY; GAS-THERMOCHROMATOGRAPHIC SEPARATION; COUPLED-CLUSTER CALCULATIONS; NEUTRON-DEFICIENT ISOTOPES; DIRAC-HARTREE-FOCK; RELATIVISTIC MOLECULAR CALCULATIONS; STATE ELECTRON CONFIGURATION; LIQUID-LIQUID EXTRACTIONS; ANION-EXCHANGE BEHAVIOR; AQUEOUS-PHASE CHEMISTRY;
D O I
10.1021/cr3002438
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A study was conducted to report advancements in the production and chemistry of the heaviest elements. The study dealt with the latest advancements in the synthesis, chemical characterization, and theoretical studies of the heaviest elements. The heaviest stable known nucleus had been reached with 208Pb and all isotopes of heavier elements, including some elements such as Bi, Th, and U were found in nature as remnants of the last nucleosynthesis process. These isotopes of heavier elements were radioactive and decay preferentially by successive α-particle and β-particle emissions back to the last stable element Pb. Accurate calculations of properties of the heavier transactinide elements and their compounds were possible due to the latest developments in relativistic quantum theory, computational algorithms, and techniques.
引用
收藏
页码:1237 / 1312
页数:76
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