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Phosphorescent, terdentate, liquid-crystalline complexes of platinum(II): Stimulus-dependent emission
被引:256
作者:
Kozhevnikov, Valery N.
[1
]
Donnio, Bertrand
[2
]
Bruce, Duncan W.
[1
]
机构:
[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
[2] Univ Strasbourg, CNRS, Inst Phys & Chim Mat Strasbourg, UMR 7504, F-67034 Strasbourg 2, France
基金:
英国工程与自然科学研究理事会;
关键词:
liquid crystals;
metallomesogens;
phosphorescence;
platinum;
D O I:
10.1002/anie.200802101
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Liquid crystals shining bright. A highly efficient platinum(II) luminophore is rendered liquid crystalline using a simple and flexible synthetic approach. Ordering in the liquid-crystalline state allows monomer emission when the characteristic for the material is exciplex-like emission. More than that, emission characteristics are subject to tribological control, with the initial state re-obtained by thermal cycling. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码:6286 / 6289
页数:4
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