A Pt-free catalyst for oxygen reduction reaction based on Fe-N multiwalled carbon nanotube composites

被引：53

作者：

Merzougui, Belabbes ^{[1
,2
]}

Hachimi, Abdouelilah ^{[1
,2
]}

Akinpelu, Akeem ^{[1
,2
]}

Bukola, Saheed ^{[1
,2
]}

Shao, Minhua ^{[3
]}

机构：

[1] King Fahd Univ Petr & Minerals, Ctr Nanotechnol CENT, Dhahran 31261, Saudi Arabia

[2] King Fahd Univ Petr & Minerals, Dept Chem, Dhahran 31261, Saudi Arabia

[3] UTC Power, South Windsor, CT 06074 USA

来源：

ELECTROCHIMICA ACTA | 2013年 / 107卷

关键词：

Non precious metal catalysts; Oxygen reduction reaction; Durability; Methanol tolerance; ELECTROCATALYST; IRON; NANOCRYSTALS; PERFORMANCE; GRAPHENE; FUTURE;

D O I：

10.1016/j.electacta.2013.06.016

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

An iron-based non-precious metal (NPM) catalyst was synthesized by chemically coating a polymer containing nitrogen, such as polyaniline (PANI), on multiwalled carbon nanotubes (MWCNTs), followed by iron complexation and heat treatment in a decomposable source of nitrogen (ammonia) at high temperature. Its excellent activities for oxygen reduction reaction (ORR) in both acidic and alkaline media were confirmed by thin film rotating disk electrode technique. Also, durability test was performed in both media. After 20,000(0.65-1.0 V) potential cycles, the half-wave potential decayed by only 40 mV in 0.1 M HClO4, while in 0.1 M KOH it gained 25 mV. In addition, no activity decay was observed by adding methanol in the acidic solution indicating its excellent tolerance to methanol oxidation. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：126 / 132

页数：7

共 50 条

[41] Nonpyrolyzed Fe-N Coordination-Based Iron Triazolate Framework: An Efficient and Stable Electrocatalyst for Oxygen Reduction Reaction [J].

Huang, Zheng-Hong ;

Xie, Nan-Hong ;

Zhang, Min ;

Xu, Bo-Qing .

CHEMSUSCHEM, 2019, 12 (01) :200-207

[42] Design of N-Coordinated Dual-Metal Sites: A Stable and Active Pt-Free Catalyst for Acidic Oxygen Reduction Reaction [J].

Wang, Jing ;

Huang, Zhengqing ;

Liu, Wei ;

Chang, Chunran ;

Tang, Haolin ;

Li, Zhijun ;

Chen, Wenxing ;

Jia, Chunjiang ;

Yao, Tao ;

Wei, Shiqiang ;

Wu, Yuen ;

Lie, Yadong .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (48) :17281-17284

[43] Computational characterization of nitrogen-doped carbon nanotube functionalized by Fe adatom and Fe substituent for oxygen reduction reaction [J].

Yoon, Sun Hee ;

Yu, Choongho ;

Han, Arum ;

Park, Hyunwoong ;

Elbashir, Nimir ;

Han, Dong Suk .

APPLIED SURFACE SCIENCE, 2019, 485 :342-352

[44] Binary Fe, Cu-doped bamboo-like carbon nanotubes as efficient catalyst for the oxygen reduction reaction [J].

Fan, Wenjun ;

Li, Zelong ;

You, Chenghang ;

Zong, Xu ;

Tian, Xinlong ;

Miao, Shu ;

Shu, Ting ;

Li, Can ;

Liao, Shijun .

NANO ENERGY, 2017, 37 :187-194

[45] A review of Fe-N/C and Co-N/C catalysts for the oxygen reduction reaction [J].

Bezerra, Cicero W. B. ;

Zhang, Lei ;

Lee, Kunchan ;

Liu, Hansan ;

Marques, Aldalea L. B. ;

Marques, Edmar P. ;

Wang, Haijiang ;

Zhang, Jiujun .

ELECTROCHIMICA ACTA, 2008, 53 (15) :4937-4951

[46] The effect of N precursors in Fe-N/C type catalysts based on activated silicon carbide derived carbon for oxygen reduction activity at various pH values [J].

Jaeger, R. ;

Kasatkin, P. E. ;

Haerk, E. ;

Teppor, P. ;

Romann, T. ;

Haermas, R. ;

Tallo, I. ;

Maeeorg, U. ;

Joost, U. ;

Paiste, P. ;

Kirsimaee, K. ;

Lust, E. .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2018, 823 :593-600

[47] Electrocatalytic Activity of Fe-N/C-TsOH Catalyst for the Oxygen Reduction Reaction in Alkaline Media [J].

Xu Li ;

Pan Guo-Shun ;

Liang Xiao-Lu ;

Luo Gui-Hai ;

Zou Chun-Li ;

Luo Hai-Mei .

ACTA PHYSICO-CHIMICA SINICA, 2014, 30 (02) :318-324

[48] Efficient Pt-free electrocatalyst for oxygen reduction reaction: Highly ordered mesoporous N and S co-doped carbon with saccharin as single-source molecular precursor [J].

Hua, Yongqi ;

Jiang, Tingting ;

Wang, Kun ;

Wu, Mingmei ;

Song, Shuqin ;

Wang, Yi ;

Tsiakaras, Panagiotis .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2016, 194 :202-208

[49] Effect of carbon nanotube diameter for the synthesis of Fe/N/multiwall carbon nanotubes and repercussions for the oxygen reduction reaction [J].

Perez-Alonso, F. J. ;

Abdel Salam, M. ;

Herranz, T. ;

Gomez de la Fuente, J. L. ;

Al-Thabaiti, S. A. ;

Basahel, S. N. ;

Pena, M. A. ;

Fierro, J. L. G. ;

Rojas, S. .

JOURNAL OF POWER SOURCES, 2013, 240 :494-502

[50] Synthesis and characterization of carbon incorporated Fe-N/carbons for methanol-tolerant oxygen reduction reaction of polymer electrolyte fuel cells [J].

Liu, Shou-Heng ;

Wu, Jyun-Ren ;

Pan, Chun-Jern ;

Hwang, Bing-Joe .

JOURNAL OF POWER SOURCES, 2014, 250 :279-285

← 1 2 3 4 5 →