Thermal analysis and simulation model of natural lithocholic acid

被引：2

作者：

Rudzki, A. ^{[1
]}

Ossowska-Chrusciel, M. D. ^{[1
]}

Ordon, M. ^{[1
,2
]}

Zajac, W. ^{[3
]}

Chrusciel, J. ^{[1
]}

机构：

[1] Siedlce Univ Nat Sci & Humanities, Inst Chem, PL-08110 Siedlce, Poland

[2] Joint Inst Nucl Res, Neutron Phys Lab, Dubna 141, Russia

[3] Polish Acad Sci, Inst Nucl Phys, PL-31342 Krakow, Poland

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2015年 / 122卷 / 01期

关键词：

Lithocholic acid; Thermal behaviour; Phase transitions; Glass state; Thermal stability; Intermolecular interactions; POLARIZED IR-SPECTRA; CRYSTALS; BEHAVIOR; PHASE;

D O I：

10.1007/s10973-015-4656-3

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Thermal behaviour of pure lithocholic acid was studied in a broad temperature range, from -20 to 200 A degrees C, using several complementary methods. The temperatures of phase transition were determined, as well as decomposition temperature. Spectroscopic differences between the stable phase and the glass state were shown and explained as resulting from different networks of hydrogen bonds. The influence of the cooling rate on the rate of the glass formation was determined. Quantum chemical calculations were performed in order to support the above conclusion.

引用

页码：55 / 64

页数：10

共 21 条

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