Two-step crystal engineering of porous nets from [Cr3(μ3-O)(RCO2)6] and [Cu3(μ3-Cl)(RNH2)6Cl6] molecular building blocks

被引：38

作者：

Elsaidi, Sameh K. ^{[1
,2
]}

Mohamed, Mona H. ^{[1
,2
]}

Wojtas, Lukasz ^{[1
]}

Cairns, Amy J. ^{[3
]}

Eddaoudi, Mohamed ^{[1
,3
]}

Zaworotko, Michael J. ^{[1
]}

机构：

[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

[2] Univ Alexandria, Fac Sci, Dept Chem, Alexandria 21321, Egypt

[3] 4700 King Abdullah Univ Sci & Technol, Thuwal 239556900, Saudi Arabia

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 74期

关键词：

METAL-ORGANIC-FRAMEWORKS; COORDINATION POLYMERS; POWDER DIFFRACTION; HYBRID FRAMEWORKS; HYDROGEN STORAGE; CARBON-DIOXIDE; ADSORPTION; STABILITY; CHEMISTRY; TOPOLOGY;

D O I：

10.1039/c3cc44133d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two porous nets have been prepared via a 2-step crystal engineering approach that links decorated trigonal prismatic [Cr-3(mu(3)-O)-(CO2)(6)] and [Cu-3(mu(3)-Cl)(RNH2)(6)Cl-6] molecular building blocks, MBBs. tp-PMBB-5-acs-1 is a rare example of a rigid acs underlying net whereas tp-PMBB-6-stp-1, an stp underlying net, exhibits free NH2 groups in its channels and a relatively high isosteric heat of adsorption for CO2.

引用

页码：8154 / 8156

页数：3

共 36 条

[1] Underlying nets in three-periodic coordination polymers: topology, taxonomy and prediction from a computer-aided analysis of the Cambridge Structural Database [J].

Alexandrov, E. V. ;

Blatov, V. A. ;

Kochetkov, A. V. ;

Proserpio, D. M. .

CRYSTENGCOMM, 2011, 13 (12) :3947-3958

[2] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[3] Heterometallic Modular Metal-Organic 3D Frameworks Assembled via New Tris-β-Diketonate Metalloligands: Nanoporous Materials for Anion Exchange and Scaffolding of Selected Anionic Guests [J].

Carlucci, Lucia ;

Ciani, Gianfranco ;

Maggini, Simona ;

Proserpio, Davide M. ;

Visconti, Marco .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (41) :12328-12341

[4] A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].

Cavka, Jasmina Hafizovic ;

Jakobsen, Soren ;

Olsbye, Unni ;

Guillou, Nathalie ;

Lamberti, Carlo ;

Bordiga, Silvia ;

Lillerud, Karl Petter .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851

[5] Interwoven metal-organic framework on a periodic minimal surface with extra-large pores [J].

Chen, BL ;

Eddaoudi, M ;

Hyde, ST ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2001, 291 (5506) :1021-1023

[6] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].

Chui, SSY ;

Lo, SMF ;

Charmant, JPH ;

Orpen, AG ;

Williams, ID .

SCIENCE, 1999, 283 (5405) :1148-1150

[7] Synthesis, X-ray crystal structures, and gas sorption properties of pillared square grid nets based on paddle-wheel motifs: Implications for hydrogen storage in porous materials [J].

Chun, H ;

Dybtsev, DN ;

Kim, H ;

Kim, K .

CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (12) :3521-3529

[8] Water Stability of Microporous Coordination Polymers and the Adsorption of Pharmaceuticals from Water [J].

Cychosz, Katie A. ;

Matzger, Adam J. .

LANGMUIR, 2010, 26 (22) :17198-17202

[9] Taxonomy of periodic nets and the design of materials [J].

Delgado-Friedrichs, Olaf ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (09) :1035-1043

[10] Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal-Organic Framework Functionalized with Ethylenediamine [J].

Demessence, Aude ;

D'Alessandro, Deanna M. ;

Foo, Maw Lin ;

Long, Jeffrey R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (25) :8784-+

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