Electrochemical Properties of Poly(3,4-ethylenedioxythiophene) Nanofiber Non-Woven Web Formed by Electrospinning

被引:12
作者
Nguyen, Hoang Dung [1 ]
Ko, Jung Min [1 ]
Kim, Hong Jung [1 ]
Kim, Seok Ki [1 ]
Cho, Seung Hyun [2 ]
Nam, Jae Do [3 ]
Lee, Jun Young [1 ,2 ]
机构
[1] Sungkyunkwan Univ, Dept Chem Engn, Suwon 440746, South Korea
[2] Sungkyunkwan Univ, Polymer Technol Inst, Suwon 440746, South Korea
[3] Sungkyunkwan Univ, Dept Polymer Sci & Engn, Suwon 440746, South Korea
关键词
Electrospinning; Poly(3,4-ethylenedioxythiophene); Electrically Conducting Non-Woven Web; Electrochemical Capacitor;
D O I
10.1166/jnn.2008.IC39
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electrically conducting nano (micro) poly(3,4-ethylenedioxythiophene) (PEDOT) fiber non-woven web was fabricated using the electrospinning technique by applying high voltage of 10 to 30 kV to the electrospinning solution. To investigate the effects of various conditions on formation and properties of PEDOT fiber non-woven web, we changed the solvent or other components and their concentrations. We used 1-propanol or 1-butanol as a solvent and poly(vinyl pyrrolidone) (PVP) as a matrix polymer to prepare the electrospinning solution. The electrical conductivity of the electrospun PEDOT non-woven web was as high as 7.5 S/cm when 1-propanol was used as the solvent. Electrochemical capacitor was assembled using one pair of the PEDOT non-woven webs as the electrodes by a simple stack method, where metal plates were used as current collectors. We observed the electrochemical charge and discharge behavior of the capacitor, confirming that the PEDOT non-woven web can be used as the electrode for flexible electrochemical capacitor.
引用
收藏
页码:4718 / 4721
页数:4
相关论文
共 12 条
[11]   OPTICAL-PROPERTIES OF CONDUCTING POLYMERS [J].
PATIL, AO ;
HEEGER, AJ ;
WUDL, F .
CHEMICAL REVIEWS, 1988, 88 (01) :183-200
[12]  
Simons H.L, 1966, US Patent, Patent No. [3,280,229, 3280229]