Preparation and Catalytic Performance of Novel Dimeric Tetranuclear Zinc Complexes in Hydroamination of Alkenes at Room Temperature

被引：13

作者：

Biyikal, Mustafa

Loehnwitz, Karolin

Roesky, Peter W. ^{[1
]}

Blechert, Siegfried ^{[2
]}

机构：

[1] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

[2] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany

来源：

SYNLETT | 2008年 / 20期

关键词：

alkenes; heterocycles; hydroamination; tetranuclear; zinc;

D O I：

10.1055/s-0028-1087418

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of two novel dimeric tetranuclear zinc complexes has been described. The application of these complexes in hydroamination of unactivated alkenes showed at room temperature high catalytic activity.

引用

页码：3106 / 3110

页数：5

共 60 条

[1] Highly diastereoselective Simmons-Smith cyclopropanation of allylic amines [J].

Aggarwal, VK ;

Fang, GY ;

Meek, G .

ORGANIC LETTERS, 2003, 5 (23) :4417-4420

[2]

[Anonymous], 2004, MULTIMETALLIC CATALY

[3] Room temperature hydroamination of N-alkenyl ureas catalyzed by a gold(I) N-heterocyclic carbene complex [J].

Bender, Christopher F. ;

Widenhoefer, Ross A. .

ORGANIC LETTERS, 2006, 8 (23) :5303-5305

[4] Intramolecular hydroamination of unactived olefins with Ti(NMe2)4 as a precatalyst [J].

Bexrud, JA ;

Beard, JD ;

Leitch, DC ;

Schafer, LL .

ORGANIC LETTERS, 2005, 7 (10) :1959-1962

[5] Reformatsky reaction in water: Evidence for a radical chain process [J].

Bieber, LW ;

Malvestiti, I ;

Storch, EC .

JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (26) :9061-9064

[6] Bimetallic fluorine-substituted anilido-aldimine zinc complexes for CO2/(cyclohexene oxide) copolymerization [J].

Bok, Taekki ;

Yun, Hoseop ;

Lee, Bun Yeoul .

INORGANIC CHEMISTRY, 2006, 45 (10) :4228-4237

[7] REGIOSELECTIVE SUBSTITUTION-REACTIONS OF ZINC SULFOLENYLATES [J].

CHOU, TS ;

TSENG, HJ .

TETRAHEDRON LETTERS, 1995, 36 (39) :7105-7108

[8] Me2Zn-mediated addition of acetylenes to aldehydes and ketones [J].

Cozzi, PG ;

Rudolph, J ;

Bolm, C ;

Norrby, PO ;

Tomasini, C .

JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (14) :5733-5736

[9] Calcium-mediated intramolecular hydroamination catalysis [J].

Crimmin, MR ;

Casely, IJ ;

Hill, MS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (07) :2042-2043

[10] Rhodium hydride formation in the presence of a bulky monophosphite ligand: a spectroscopic and solid-state investigation [J].

Crous, R ;

Datt, M ;

Foster, D ;

Bennie, L ;

Steenkamp, C ;

Huyser, J ;

Kirsten, L ;

Steyl, G ;

Roodt, A .

DALTON TRANSACTIONS, 2005, (06) :1108-1116

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