Design of chiral sulfoxide-Schiff base hybrids and their application in Cu-catalyzed asymmetric Henry reactions

被引：41
|
作者：
Cheng, Hong-Gang [1 ]
Lu, Liang-Qiu [1 ]
Wang, Tao [1 ]
Chen, Jia-Rong [1 ]
Xiao, Wen-Jing [1 ]
机构：
[1] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Hubei, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 45期
基金：
美国国家科学基金会;
关键词：
DIELS-ALDER REACTIONS; NUCLEOPHILIC-SUBSTITUTION REACTIONS; ELECTRON-DEFICIENT OLEFINS; ARYLBORONIC ACIDS; NITROALDOL REACTION; ENANTIOSELECTIVE ADDITION; UNFUNCTIONALIZED OLEFINS; AROMATIC-ALDEHYDES; COPPER-COMPLEXES; ALPHA-KETOESTERS;
D O I：
10.1039/c2cc31907a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new class of chiral sulfoxide-Schiff base ligands has been developed by the rational combination of two privileged chiral backbones. These sulfoxide-Schiff base ligands were found to be highly efficient for Cu-catalyzed asymmetric Henry reactions (up to 98% yield and 96% ee).
引用
收藏
页码：5596 / 5598
页数：3
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