Enzymatic biodiesel production: Technical and economical considerations

被引:158
作者
Nielsen, Per Munk [1 ]
Brask, Jesper [1 ]
Fjerbaek, Lene [2 ]
机构
[1] Novozymes AS, DK-2880 Bagsvaerd, Denmark
[2] Univ So Denmark, Odense, Denmark
关键词
biodiesel; fatty acid alkyl esters; immobilized enzyme; lipase; transesterification;
D O I
10.1002/ejlt.200800064
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
It is well documented in the literature that enzymatic processing of oils and fats for biodiesel is technically feasible. However, with very few exceptions, enzyme technology is not currently used in commercial-scale biodiesel production. This is mainly clue to non-optimized process design and a lack of available cost-effective enzymes. The technology to re-use enzymes has typically proven insufficient for the processes to be competitive. However, literature data documenting the productivity of enzymatic biodiesel together with the development of new immobilization technology indicates that enzyme catalysts can become cost effective compared to chemical processing. This work reviews the enzymatic processing of oils and fats into biodiesel with focus on process design and economy.
引用
收藏
页码:692 / 700
页数:9
相关论文
共 46 条
[1]  
Abo M., 2006, Production of fatty acid alkyl esters by use of two lipolytic enzymes, Patent No. [WO 2006/072256, 2006072256]
[2]   Enzymatic approach to biodiesel production [J].
Akoh, Casimir C. ;
Chang, Shu-Wei ;
Lee, Guan-Chiun ;
Shaw, Jei-Fu .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2007, 55 (22) :8995-9005
[3]   Regeneration of immobilized Candida antarctica lipase for transesterification [J].
Chen, JW ;
Wu, WT .
JOURNAL OF BIOSCIENCE AND BIOENGINEERING, 2003, 95 (05) :466-469
[4]   Biodiesel from microalgae [J].
Chisti, Yusuf .
BIOTECHNOLOGY ADVANCES, 2007, 25 (03) :294-306
[5]  
Christensen MW, 2006, WORLD C IND BIOT BIO
[6]   Optimization of enzymatic production of biodiesel from castor oil in organic solvent medium [J].
Débora de Oliveira ;
Marco Di Luccio ;
Carina Faccio ;
Clarissa Dalla Rosa ;
João Paulo Bender ;
Nádia Lipke ;
Silvana Menoncin ;
Cristiana Amroginski ;
José Vladimir de Oliveira .
Applied Biochemistry and Biotechnology, 2004, 115 (1-3) :771-780
[7]  
DEGREYT W, 2007, INT C BIOD VIENN AUS
[8]   Enzymatic production of alkyl esters through alcoholysis: A critical evaluation of lipases and alcohols [J].
Deng, L ;
Xu, XB ;
Haraldsson, GG ;
Tan, TW ;
Wang, F .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2005, 82 (05) :341-347
[9]   Comparative study on lipase-catalyzed transformation of soybean oil for biodiesel production with different acyl acceptors [J].
Du, W ;
Xu, YY ;
Liu, DH ;
Zeng, J .
JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2004, 30 (3-4) :125-129
[10]   Mechanism exploration during lipase-mediated methanolysis of renewable oils for biodiesel production in a tert-butanol system [J].
Du, Wei ;
Liu, Dehua ;
Li, Lilin ;
Dai, Lingmei .
BIOTECHNOLOGY PROGRESS, 2007, 23 (05) :1087-1090