Synthesis and rearrangement of (Z)-allylic trichloroacetimidates.

被引：10

作者：

Martin, C ^{[1
]}

Bortolussi, M ^{[1
]}

Bloch, R ^{[1
]}

机构：

[1] Univ Paris Sud, Inst Chim Mol Orsay, CNRS, Lab Carbocycles, F-91405 Orsay, France

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 19期

关键词：

3,3] rearrangements; allylic imidates; allylic amides; chirality transfer;

D O I：

10.1016/S0040-4039(99)00626-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient synthesis of (Z)-allylic trichloroacetimidates starting from lactol 1 is described. Thermal [3,3] rearrangement of these imidates occurred with excellent chirality transfer to give allylic amides. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：3735 / 3736

页数：2

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