Alignment by Langmuir/Schaefer Monolayers of Bent-Core Liquid Crystals

被引:6
作者
Iglesias, Wilder [1 ]
Smith, Timothy J. [2 ]
Basnet, Prem B. [3 ]
Stefanovic, Sharon [3 ]
Tschierske, Carsten [4 ]
Lacks, Daniel J. [2 ]
Jakli, Antal [1 ]
Mann, Elizabeth K. [3 ]
机构
[1] Kent State Univ, Inst Liquid Crystal, Kent, OH 44242 USA
[2] Case Western Reserve Univ, Cleveland, OH 44106 USA
[3] Kent State Univ, Dept Phys, Kent, OH 44242 USA
[4] Univ Halle Wittenberg, Inst Organ Chem, D-06120 Halle, Germany
基金
美国国家科学基金会;
关键词
AIR-WATER-INTERFACE; ACHIRAL MOLECULES; BREWSTER-ANGLE; SURFACES; BEHAVIOR; SYSTEMS; PHASE; FIELD; RING;
D O I
10.1080/00150193.2012.684977
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Bulk alignment of liquid crystalline phases is achieved using self-organized thin films of bent-core mesogens transferred to a glass substrate by Inverse-Langmuir-Schaefer (ILS). We discuss the importance of the architecture of the aligning molecules (hydrophilic/hydrophobic balance for film stability as well as other structural factors) and show the dependence of the density of the monolayer with the alignment induced by it. These results are compared with molecular simulations for further understanding of molecular packing and interfacial interactions.
引用
收藏
页码:141 / 149
页数:9
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