catena-Poly[[lead(II)-bis(μ2-quinolin-8-olato)-κ3N,O:O;κ3O:N,O] N,N-dimethylformamide hemisolvate]

被引：0

作者：

Ghaemi, Akbar ^{[2
]}

Dadkhah, Zohreh ^{[2
]}

Ng, Seik Weng ^{[1
,3
]}

Tiekink, Edward R. T. ^{[1
]}

机构：

[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

[2] Islamic Azad Univ, Dept Chem, Saveh Branch, Saveh, Iran

[3] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah, Saudi Arabia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷

关键词：

data-toparameter ratio = 14.2; disorder in solvent or counterion; mean σ(C-C) = 0.006 Å; R factor = 0.021; single-crystal X-ray study; T = 100 K; wR factor = 0.049;

D O I：

10.1107/S1600536812002796

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, {[Pb(C9H6NO)(2)]center dot 0.5C(3)H(7)NO}(n), comprises Pb(quinolate)(2) and half a dimethylformamide molecule (which is disordered about a centre of inversion). The quinolate ligands N,O-chelate to a Pb-II ion and simultaneously bridge a neighbouring Pb-II ion to form a polymeric chain along [100] comprising Pb-linked Pb2O2 distorted rhombi. These chains pack to form a square grid, with the channels thus defined occupied by the disordered solvent molecules.

引用

页码：M210 / U1171

页数：13

共 7 条

[1]

Agilent, 2010, CRYSALIS PRO

[2]

Brandenburg K., 2006, DIAMOND

[3]

Farrugia L.J., 1997, J. Appl. Crystallogr., V30, P565, DOI [10.1107/S0021889897003117, DOI 10.1107/S0021889897003117]

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Ghaemi, Akbar ;

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ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 :M97-U228

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JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2010, 43 :920-925

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Zhu, LH ;

Zeng, MH ;

Ng, SW .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 :M1082-M1084

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