Cobalt-catalyzed arylation of aldimines via directed C-H bond functionalization: addition of 2-arylpyridines and self-coupling of aromatic aldimines

被引：105

作者：

Gao, Ke ^{[1
]}

Yoshikai, Naohiko ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 36期

基金：

新加坡国家研究基金会;

关键词：

UNSATURATED MOLECULES; SELECTIVE SYNTHESIS; ALKYNES; ARYL; ALDEHYDES; INSERTION; AUTOXIDATION; ACTIVATION; ISOINDOLES; IMINES;

D O I：

10.1039/c2cc31114c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cobalt-N-heterocyclic carbene catalyst, in combination with an appropriate Grignard reagent, promotes a chelation-assisted aromatic C-H functionalization reaction via addition to an aromatic aldimine.

引用

页码：4305 / 4307

页数：3

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