Solar Hydrogen Generation by Silicon Nanowires Modified with Platinum Nanoparticle Catalysts by Atomic Layer Deposition

被引:105
作者
Dai, Pengcheng [1 ,2 ]
Xie, Jin [1 ]
Mayer, Matthew T. [1 ]
Yang, Xiaogang [1 ]
Zhan, Jinhua [2 ]
Wang, Dunwei [1 ]
机构
[1] Boston Coll, Merkert Chem Ctr, Dept Chem, Chestnut Hill, MA 02467 USA
[2] Shandong Univ, Dept Chem, Jinan 250100, Shandong, Peoples R China
基金
中国国家自然科学基金; 美国国家科学基金会;
关键词
hydrogen; photoelectrochemistry; silicon nanowires; solar energy conversion; water splitting; JUNCTION; CELLS;
D O I
10.1002/anie.201303813
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Covered with Pt: A uniform catalyst profile that ensures effective radial charge collection from high-aspect-ratio Si nanowires was achieved by atomic layer deposition of Pt nanoparticles. The resulting photoelectrode permits the measurement of high photovoltages and low overpotentials, and leads to very good stability against photooxidation of Si nanowires in solar water-reduction reactions. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:11119 / 11123
页数:5
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