Growth and electrical properties of Mg:α-LiIO3 crystal

被引:8
作者
Du, YinXiao [1 ]
Sun, Yuping [1 ]
Chen, W. C. [1 ]
Chen, X. L. [1 ]
Zhang, D. F. [1 ]
机构
[1] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100080, Peoples R China
基金
中国国家自然科学基金;
关键词
crystal growth; dielectric constant; doping; electrical conductivity; electrical properties; full-width at half-maximum; segregation coefficient; magnesium;
D O I
10.1016/j.jcrysgro.2006.03.034
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The 20-70 ppm Mg2+ -doped alpha-lithium iodate (Mg:alpha-LiIO3) Crystals were successfully grown by aqueous solution method. Transparent and well-crystallized hexagonal prisms were obtained by evaporation with controlled condensation of water solutions at a constant temperature of 60 degrees C. An intriguing finding is that the segregation coefficient of Mg2+ ions in the Mg(70ppm):alpha-LiIO3 crystal is up to 2.5, suggesting the Mg2+ ions are easily incorporated into crystal lattice during the crystal growth process. The physical properties of electrical conductivity, dielectric and piezoelectric characterization are investigated on the Mg(70ppm):alpha-LiIO3 crystals. In comparison with the pure alpha-LiIO3 crystal, the electrical conductivity and the dielectric characterization of the Mg(70ppm):alpha-LiIO3 crystal are enhanced significantly, but its piezoelectric coefficient d(33) decreases from 47 to 5.5 pC/N. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:424 / 427
页数:4
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