Enhanced stability and conductivity of polypyrrole film prepared electrochemically in the presence of centrifugal forces

被引:16
作者
Eftekhari, A [1 ]
机构
[1] Electrochem Res Ctr, Tehran, Iran
关键词
conductive polymer; highly stable film; enhanced conductivity; centrifugal fields; squeezing effect;
D O I
10.1016/j.synthmet.2003.08.002
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Electrochemical polymerization/deposition of conductive polymers under centrifugal fields was introduced as an efficient method to enhance physical properties of the conductive polymers synthesized. The approach was typically employed for the preparation of thin films of polypyrrole. The results obtained from the experimental measurements obviously showed that the electroactive films formed in the presence of stronger centrifugal forces have significantly higher stability and electronic conductivity. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:305 / 308
页数:4
相关论文
共 20 条
[1]   Electrooxidative copolymerization of aniline with o-aminobenzonitrile in centrifugal fields [J].
Atobe, M ;
Sekido, M ;
Fuchigami, T ;
Nonaka, T .
CHEMISTRY LETTERS, 2003, 32 (02) :166-167
[2]   Chemistry in centrifugal fields - Part 1. Electrooxidative polymerization of aniline [J].
Atobe, M ;
Hitose, S ;
Nonaka, T .
ELECTROCHEMISTRY COMMUNICATIONS, 1999, 1 (07) :278-281
[3]   ELECTROCHEMICAL POLYMERIZATION OF PYRROLE [J].
DIAZ, AF ;
KANAZAWA, KK ;
GARDINI, GP .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (14) :635-636
[4]   Improving Cu metallization of Si by electrodeposition under centrifugal fields [J].
Eftekhari, A .
MICROELECTRONIC ENGINEERING, 2003, 69 (01) :17-25
[5]   Soft magnetic CoNiFe films electrodeposited under centrifugal forces [J].
Eftekhari, A .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2003, 36 (10) :1183-1187
[8]   Enhanced stability of hexacyanoferrate-based modified electrodes prepared under centrifugal fields [J].
Eftekhari, A .
MENDELEEV COMMUNICATIONS, 2002, (05) :206-207