Structure and Luminescence Properties of Antimony(III) Complex Compounds

被引:34
作者
Sedakova, T. V. [1 ]
Mirochnik, A. G. [1 ]
Karasev, V. E. [1 ]
机构
[1] Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia
基金
俄罗斯基础研究基金会;
关键词
D O I
10.1134/S0030400X08100056
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The influence of the structure of the anion sublattice on the spectral luminescence properties is investigated using the example of antimony(III) complex compounds with outer-sphere organic cations. It is established that the factors favorable for the enhancement of the luminescence of antimony(III) ions are the island structure of the anion sublattice with minimum distortions of the antimony(III) coordination polyhedron and closely spaced energy levels of the outer-sphere organic cation and the antimony(III) ion.
引用
收藏
页码:517 / 523
页数:7
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