Pseudomorphic Transformation of Highly Ordered Mesoporous Co3O4 to CoO via Reduction with Glycerol

被引：119

作者：

Tueysuez, Harun ^{[1
]}

Liu, Yong ^{[1
]}

Weidenthaler, Claudia ^{[1
]}

Schueth, Ferdi ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 43期

关键词：

D O I：

10.1021/ja806202v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this report, we describe the exploration of possibilities for a pseudomorphic reduction of ordered mesoporous metal oxides by high temperature treatment with glycerol, which was most thoroughly studied as an example of the reaction of Co3O4 to CoO. It was found that the glycerol process is a gentle reduction procedure, which maintains the framework topology on the mesoscale while changing the oxidation state and the structure at the atomic scale.

引用

页码：14108 / +

页数：4

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