Gold(III) chloride and acetate complexes with bipyridine and phenanthroline

被引：14

作者：

Akhmadullina, N. S. ^{[1
]}

Churakov, A. V. ^{[2
]}

Retivov, V. M. ^{[3
]}

Sandu, R. A. ^{[3
]}

Shishilov, O. N. ^{[2
]}

机构：

[1] Russian Acad Sci, Baikov Inst Met & Mat Sci, Moscow 119991, Russia

[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

[3] State Res Inst Chem Reagents & Special Pur Subst, Moscow, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2012年 / 38卷 / 09期

关键词：

GOLD CATALYSIS; ALKYNES; DIVERSITY; PLATINUM; LIGAND;

D O I：

10.1134/S1070328412080015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cationic-anionic chloride complexes of gold(III), [(L)AuCl2]BF4 (L = 2,2'-bipyridine and 1,10-phenanthroline (Phen)), are synthesized. Their reactions and the reactions of complex [(Phen)AuCl2]Cl with silver(I) and sodium acetates are studied. The chloride ligands in complexes [(L)AuCl2]BF4 are easily substituted by the acetate ligands in the reaction with silver(I) acetate to form new carboxylate complexes [(L)Au(OAc)(2)]BF4. The reaction of complex [(Phen)AuCl2]Cl with sodium acetate in glacial acetic acid affords binary complex salt [(Phen)AuCl2][AuCl4], which is characterized by single-crystal X-ray diffraction analysis.

引用

页码：589 / 595

页数：7

共 30 条

[1]

Ahmadi R., 2008, ACTA CRYSTALLOGR E, V64, P9

[2] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[3] An investigation of the thermal decomposition of gold acetate [J].

Bakrania, S. D. ;

Rathore, G. K. ;

Wooldridge, Margaret S. .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 95 (01) :117-122

[4]

Bellamy L.J., 1962, INFRARED SPECTRA COM

[5] THE REACTION OF GOLD(III) WITH SOME BIDENTATE COORDINATING GROUPS [J].

BLOCK, BP ;

BAILAR, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (10) :4722-4725

[6] Synthesis and structure of products of interaction of H[AuCl4] with H2DMG and pyridine [J].

Bourosh, Paulina ;

Bologa, Olga ;

Simonov, Yurii ;

Gerbeleu, Nicolae ;

Lipkowski, Janusz ;

Gdaniec, Maria .

INORGANICA CHIMICA ACTA, 2007, 360 (10) :3250-3254

[7]

Christian B., 2005, ANGEW CHEM-GER EDIT, V44, P2328

[8] Chemical and biological studies of the dichloro(2-phenylpyridine) gold(III) complex and its derivatives [J].

Fan, DM ;

Yang, CT ;

Ranford, JD ;

Lee, PF ;

Vittal, JJ .

DALTON TRANSACTIONS, 2003, (13) :2680-2685

[9] Catalytic carbophilic activation:: Catalysis by platinum and gold π acids [J].

Fuerstner, Alois ;

Davies, Paul W. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (19) :3410-3449

[10] Ligand effects in homogeneous Au catalysis [J].

Gorin, David J. ;

Sherry, Benjamin D. ;

Toste, F. Dean .

CHEMICAL REVIEWS, 2008, 108 (08) :3351-3378

← 1 2 3 →