Phosphorodithioate-functionalized ionic liquids: Synthesis and physicochemical properties characterization

被引：5

作者：

Shultz, Zachary ^{[1
]}

Gaitor, Jamie C. ^{[1
]}

Burton, Rachel D. ^{[1
]}

Regner, Matthew ^{[1
]}

Sheng, Yinghong ^{[1
]}

Mirjafari, Arsalan ^{[1
]}

机构：

[1] Florida Gulf Coast Univ, Dept Chem & Phys, Ft Myers, FL 33965 USA

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2019年 / 276卷

关键词：

Ionic liquids; Phosphorodithioate; Task-specific ionic liquids; Palladium binding; COMPLEXES;

D O I：

10.1016/j.molliq.2018.11.166

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This study focuses on preparation and characterization of physicochemical properties of a series of phosphorodithioate-bearing ionic liquids. They displayed low glass transition temperatures, high thermal stability, and were hydrophobic in character. The results of their ligation capability toward Pd(II) via(31)P NMR spectroscopy is also presented. The synthetic strategy has the potential to impart (EtO)(2)P(=S)S functionality to ionic liquids by providing the flexibility to incorporate long linkers and task-specific anion to enhance hydrophobicity. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：334 / 337

页数：4

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