The thermophysical properties of binary mixtures of molten alkali fluoride salts. Part II: Correlations for the transport properties in reduced form

被引:0
作者
Griffard, Cory [1 ]
Penoncello, Steven G. [1 ,2 ]
Crepeau, John C. [1 ,2 ]
机构
[1] Univ Idaho, Ctr Appl Thermodynam Studies, Moscow, ID 83844 USA
[2] Univ Idaho, Dept Mech Engn, Moscow, ID 83844 USA
关键词
Molten salts; Transport properties; Fluoride mixtures; BORN REPULSIVE PARAMETERS; CORRESPONDING STATES; IONIC SIZES; HALIDES; LAW; VISCOSITY; DENSITY;
D O I
10.1016/j.pnucene.2013.08.009
中图分类号
TL [原子能技术]; O571 [原子核物理学];
学科分类号
0827 ; 082701 ;
摘要
Correlations for predicting the transport properties of molten salts and their binary mixtures are presented as functions of temperature. The molten salt mixtures considered contained lithium fluoride (LiF), sodium fluoride (NaF), and potassium fluoride (KF). The properties and temperature were reduced using potential parameters. Mixing rules were used to determine these parameters for the mixtures. Certain parameters for the correlations were determined for each property by non-linear regression between experimental data and values calculated from the correlations. The correlations are valid in the liquid phase for temperatures ranging from 765 K to about 1280 K, depending on the salt. Comparison of the experimental data to values calculated from the correlations indicates that viscosities can be calculated to within 3%, surface tensions within 2%, and thermal conductivities within +/- 3%. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:119 / 127
页数:9
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