Four new cycloartane glycosides from Thalictrum fortunei

被引：11
|
作者：
Zhang, XT
Zhang, LH
Ye, WC [1 ]
Zhang, XL
Yin, ZQ
Zhao, SX
Yao, XS
机构：
[1] China Pharmaceut Univ, Dept Phytochem, Nanjing 210008, Peoples R China
[2] Jinan Univ, Inst Tradit Chinese Med & Nat Prod, Guangzhou 510632, Peoples R China
[3] Jiangsu Univ, Dept Phytochem, Zhenjiang 212013, Peoples R China
来源：
CHEMICAL & PHARMACEUTICAL BULLETIN | 2006年 / 54卷 / 01期
关键词：
Thalictrum fortunei; Ranunculaceae; cycloartane glycoside;
D O I：
10.1248/cpb.54.107
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
Four new cycloartane glycosides were isolated from the aerial parts of Thalictrum fortunei (Ranunculaceae). The chemical structures of these new glycosides were elucidated as 3-O-beta-o-glucopyranosyl-(1 -> 4)-beta-D-fucopyranosyl (22S,24Z)-cycloart-24-en-3 beta,22,26-triol 26-O-beta-D-glucopyranoside, 3-O-beta-D-glucopyranosyl-(1 -> 4)-beta-D-fucopyranosyl (22S,24Z)-cycloart-24-en-3 beta,22,26-triol 26-O-beta-D-quinovopyranosyl-(1 -> 6)-beta-D-glucopyranoside, 3-O-beta-D-glucopyranosyl-(1 -> 4)-beta-D-fucopyranosyl (22S,24Z)-cycloart-24-en-beta,22,26-triol 26-O-beta-D-xylopyranosyl(1 -> 6)-beta-D-glucopyranoside, and 3-O-beta-o-glucopyranosyl-(1 -> 4)-beta-D-fucopyranosyl (22S,24Z)-cycloart-24-en-3 beta,22,26-triol 26-O-alpha-L-arabinopyranosyl-(1 -> 6)-beta-D-glucopyranoside by extensive NMR methods, HR-ESI-MS, and hydrolysis. This is the first report of (22S,24Z)-3 beta,22,26-trihydroxycycloartan-24-ene (thelictogenin A, 5) 14 being glycosylated at C-26.
引用
收藏
页码：107 / 110
页数：4
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