Hydrothermal synthesis and characterization of LaIII and CuII coordination polymers with 5-nitroisophthalic acid (H2Nip), [La2(μ-NiP)(μ-SO4)2(H2O)5]n and {[Cu3(μ-OH)2(μ-NiP)2(μ-H2O)2]•2H2O}n

被引：6

作者：

Xiao, Hong-Ping ^{[1
]}

Li, Xin-Hua ^{[1
]}

Shi, Qian ^{[1
]}

Zhang, Wei-Bing ^{[1
]}

Wang, Jia-Guo ^{[1
]}

Morsali, Ali ^{[2
]}

机构：

[1] Wenzhou Univ, Sch Chem & Mat Sci Engn, Wenzhou, Peoples R China

[2] Tarbiat Modares Univ, Sch Sci, Dept Chem, Tehran 141554838, Iran

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 18期

关键词：

Lanthanide(III); Copper(II); 5-nitroisophthalate; coordination polymer;

D O I：

10.1080/00958970801986809

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

3D La-III and 2D Cu-II coordination polymers with 5-nitroisophthalate anions, [La-2(mu-Nip) (mu-SO4)(2)(H2O)(5)](n) (1) and {[Cu-3(mu-OH)(2)(mu Nip)(2)(mu-H2O)(2)]center dot 2H(2)O}(n) (2) have been synthesized, characterized and studied by X-ray crystallography. The La atoms have eight-coordinate geometries in distorted square antiprism environments and the Cu atoms have five- and six-coordinate geometries with distorted square pyramidal anti octahedral environments. Self-assembly of these compounds in the solid state occurs through coordination and hydrogen bonding.

引用

页码：2905 / 2915

页数：11

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