Current and future applications of nanoclusters

被引:380
作者
Schmid, G [1 ]
Bäumle, M [1 ]
Geerkens, M [1 ]
Helm, I [1 ]
Osemann, C [1 ]
Sawitowski, T [1 ]
机构
[1] Univ Essen Gesamthsch, Inst Anorgan Chem, D-45117 Essen, Germany
关键词
D O I
10.1039/a801153b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This article deals with some recent developments in metal and in semiconducting nanocluster science, Our studies on the properties, mainly of metal nanoclusters, with respect to future and also to current applications are reviewed, including a series of unpublished results, The general properties of metal clusters of one up to a few nanometers are discussed on the basis of numerous physical investigations in the course of the last few years. Quantum size effects open the door to novel future technologies. The success of future applications of nanoclusters will strongly depend on the availability of three-, two- or one-dimensionally organized materials. Our own very recent results are promising, but also indicate that much more work will be necessary. Much more realistic is the use of metal nanoclusters in heterogeneous catalysis. Finally, novel developments in generating semiconducting nanomaterials in transparent, nanoporous alumina membranes are discussed. CdS and GaN can easily be prepared inside the pores to give photoluminescent foils of unlimited size.
引用
收藏
页码:179 / 185
页数:7
相关论文
共 39 条
  • [31] THE APPLICATION OF AU-55 CLUSTERS AS QUANTUM DOTS
    SIMON, U
    SCHON, G
    SCHMID, G
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1993, 32 (02) : 250 - 254
  • [32] Direct probe of size-dependent electronic relaxation in single-sized Au and nearly monodisperse Pt colloidal nano-particles
    Smith, BA
    Zhang, JZ
    Giebel, U
    Schmid, G
    [J]. CHEMICAL PHYSICS LETTERS, 1997, 270 (1-2) : 139 - 144
  • [33] PHOTOCHEMISTRY OF COLLOIDAL SEMICONDUCTORS .20. SURFACE MODIFICATION AND STABILITY OF STRONG LUMINESCING CDS PARTICLES
    SPANHEL, L
    HAASE, M
    WELLER, H
    HENGLEIN, A
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (19) : 5649 - 5655
  • [34] Gold nanoparticles in micellar poly(styrene)-b-poly(ethylene oxide) films-size and interparticle distance control in monoparticulate films
    Spatz, JP
    Roescher, A
    Moller, M
    [J]. ADVANCED MATERIALS, 1996, 8 (04) : 337 - 340
  • [35] Mineralization of gold nanoparticles in a block copolymer microemulsion
    Spatz, JP
    Mossmer, S
    Moller, M
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (12) : 1552 - 1555
  • [36] EFFECTS OF ANNEALING IN CD OR S VAPOR ON PHOTOELECTRIC PROPERTIES OF CDS SINGLE-CRYSTALS
    SUSA, N
    WATANABE, H
    WADA, M
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS, 1976, 15 (12) : 2365 - 2370
  • [37] Quantum-size effects in the thermodynamic properties of metallic nanoparticles
    Volokitin, Y
    Sinzig, J
    deJongh, LJ
    Schmid, G
    Vargaftik, MN
    Moiseev, II
    [J]. NATURE, 1996, 384 (6610) : 621 - 623
  • [38] COLLOIDAL SEMICONDUCTOR Q-PARTICLES - CHEMISTRY IN THE TRANSITION REGION BETWEEN SOLID-STATE AND MOLECULES
    WELLER, H
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (01): : 41 - 53
  • [39] Nanocrystal gold molecules
    Whetten, RL
    Khoury, JT
    Alvarez, MM
    Murthy, S
    Vezmar, I
    Wang, ZL
    Stephens, PW
    Cleveland, CL
    Luedtke, WD
    Landman, U
    [J]. ADVANCED MATERIALS, 1996, 8 (05) : 428 - 433