Spontaneous mirror symmetry breaking in a re-entrant isotropic liquid

被引:24
作者
Dressel, Christian [1 ]
Weissflog, Wolfgang [1 ]
Tschierske, Carsten [1 ]
机构
[1] Univ Halle Wittenberg, Inst Chem, D-06120 Halle, Germany
关键词
BENT-CORE MESOGENS; NEMATIC PHASE; CRYSTALLINE; BEHAVIOR; TRANSITION; MOLECULES; DYNAMICS; LAMELLAR; ORDER; STATE;
D O I
10.1039/c5cc06843f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An achiral double-swallow tailed tetracatenar compound forms a re-entrant isotropic liquid between a bicontinuous cubic phase and a nematic liquid crystalline phase. This isotropic liquid was found to represent a conglomerate of two immiscible chiral liquids. The chirality is retained and eventually becomes uniform at the transition to the cubic I432 phase.
引用
收藏
页码:15850 / 15853
页数:4
相关论文
共 38 条
  • [11] Dressel C, 2014, NAT CHEM, V6, P971, DOI [10.1038/nchem.2039, 10.1038/NCHEM.2039]
  • [12] The cybotactic nematic phase of bent-core mesogens: state of the art and future developments
    Francescangeli, Oriano
    Vita, Francesco
    Samulski, Edward T.
    [J]. SOFT MATTER, 2014, 10 (39) : 7685 - 7691
  • [13] ORIENTATIONAL ORDER PARAMETER AND SHAPE ANISOTROPY OF THE MICELLES IN A LYOTROPIC NEMATIC PHASE
    GALERNE, Y
    NETO, AMF
    LIEBERT, L
    [J]. PHYSICAL REVIEW A, 1985, 31 (06): : 4047 - 4048
  • [14] Fluorinated metallomesogens - lamellar versus columnar phase formation
    Glebowska, Agata
    Przybylski, Pawel
    Winek, Marta
    Krzyczkowska, Paulina
    Krowczynski, Adam
    Szydlowska, Jadwiga
    Pociecha, Damian
    Gorecka, Ewa
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (10) : 1395 - 1398
  • [15] LATTICE MELTING AT THE CLEARING POINT IN FRUSTRATED SYSTEMS
    GOODBY, JW
    DUNMUR, DA
    COLLINGS, PJ
    [J]. LIQUID CRYSTALS, 1995, 19 (05) : 703 - 709
  • [16] Enantioselective segregation in achiral nematic liquid crystals
    Görtz, V
    Goodby, JW
    [J]. CHEMICAL COMMUNICATIONS, 2005, (26) : 3262 - 3264
  • [17] Tetragonal Phase of 6-Oxoverdazyl Bent-Core Derivatives with Photoinduced Ambipolar Charge Transport and Electrooptical Effects
    Jasinski, Marcin
    Pociecha, Damian
    Monobe, Hirosato
    Szczytko, Jacek
    Kaszynski, Piotr
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (42) : 14658 - 14661
  • [18] Nematic phases of bent-core mesogens
    Keith, Christina
    Lehmann, Anne
    Baumeister, Ute
    Prehm, Marko
    Tschierske, Carsten
    [J]. SOFT MATTER, 2010, 6 (08) : 1704 - 1721
  • [19] Recent Progress in the Synthesis and Structural Clarification of Thermotropic Cubic Phases
    Kutsumizu, Shoichi
    [J]. ISRAEL JOURNAL OF CHEMISTRY, 2012, 52 (10) : 844 - 853
  • [20] Structure and Dynamics of Reentrant Nematics: Any Open Questions after Almost 40 Years?
    Mazza, Marco G.
    Schoen, Martin
    [J]. INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2011, 12 (08) : 5352 - 5372