Spontaneous mirror symmetry breaking in a re-entrant isotropic liquid

被引:24
作者
Dressel, Christian [1 ]
Weissflog, Wolfgang [1 ]
Tschierske, Carsten [1 ]
机构
[1] Univ Halle Wittenberg, Inst Chem, D-06120 Halle, Germany
关键词
BENT-CORE MESOGENS; NEMATIC PHASE; CRYSTALLINE; BEHAVIOR; TRANSITION; MOLECULES; DYNAMICS; LAMELLAR; ORDER; STATE;
D O I
10.1039/c5cc06843f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An achiral double-swallow tailed tetracatenar compound forms a re-entrant isotropic liquid between a bicontinuous cubic phase and a nematic liquid crystalline phase. This isotropic liquid was found to represent a conglomerate of two immiscible chiral liquids. The chirality is retained and eventually becomes uniform at the transition to the cubic I432 phase.
引用
收藏
页码:15850 / 15853
页数:4
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