Solubility of 1-Fluoro-4-(methylsulfonyl)benzene in Five Pure Organic Solvents at Temperatures from (288.40 to 331.50) K

被引:5
作者
Qian, Chao [1 ,2 ]
Wang, Yayun [1 ]
Chen, Xinzhi [1 ,2 ]
机构
[1] Zhejiang Univ, Dept Chem & Biol Engn, Hangzhou 310027, Zhejiang, Peoples R China
[2] Zhejiang Univ, State Key Lab Chem Engn, Hangzhou 310027, Zhejiang, Peoples R China
基金
中国国家自然科学基金; 高等学校博士学科点专项科研基金;
关键词
Benzene - Organic solvents - Ethanol - Toluene - Acetone - Atmospheric pressure - Chlorine compounds;
D O I
10.1021/je400965y
中图分类号
O414.1 [热力学];
学科分类号
摘要
The solubilities of 1-fluoro-4-(methylsulfonyl)benzene in five pure organic solvents (ethanol, ethyl acetate, acetone, toluene, and chloroform) at temperatures ranging from (288.40 to 331.50) K under atmospheric pressure were measured experimentally by the dynamic method with a laser monitoring apparatus. It was found that the solubilities in different solvents decreased in the order chloroform > acetone > ethyl acetate > toluene > ethanol. The experimental data were well-correlated using the modified Apelblat equation, with average relative deviations of less than 2.92 % and root-mean-square deviations of no more than 0.30 %.
引用
收藏
页码:1254 / 1256
页数:3
相关论文
共 9 条
[1]   Solubility of 6-Chloropyridazin-3-amine in Different Solvents [J].
Cao, Xin-Xiang ;
Liu, Jin-Qiang ;
Lv, Teng-Teng ;
Yao, Jing-Cai .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2012, 57 (05) :1509-1514
[2]   Solubilities of 3-Methoxy-N-phenylaniline and 3-(Methylthio)-N-phenylaniline in Five Organic Solvents (285 K to 333.75 K) [J].
Jia, Yin-xia ;
Qian, Chao ;
Chen, Xin-zhi ;
He, Chao-hong .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2012, 57 (05) :1581-1585
[3]   Copper-catalyzed sulfonylation of arylboronic acids in ionic liquids [J].
Kantam, M. Lakshmi ;
Neelima, B. ;
Sreedhar, B. ;
Chakravarti, Rajashree .
SYNLETT, 2008, (10) :1455-1458
[4]   Solubility of 4-(3,4-dichlorophenyl)-1-tetralone in some organic solvents [J].
Li, Qun-Sheng ;
Li, Zhao ;
Wang, Shui .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (01) :151-153
[5]   Selective Oxidation of Sulfides to Sulfones Using H2O2 and Anderson-Type Hexamolybdochromate(III) as Catalyst [J].
Supale, Amit R. ;
Gokavi, Gavisiddappa S. .
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2010, 185 (04) :725-731
[6]   Silver-Catalyzed Late-Stage Fluorination [J].
Tang, Pingping ;
Furuya, Takeru ;
Ritter, Tobias .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (34) :12150-12154
[7]   Solubility of Imperatorin in Ethyl Acetate, Ethanol, Methanol, n-Hexane, and Petroleum Ether from (278.2 to 318.2) K [J].
Wang, Long-Hu ;
Mei, Yan-Hong ;
Yu, Li-yan ;
Liu, Xue-Song ;
Chen, Yong .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2011, 56 (05) :2329-2331
[8]   Solubilities of 4,4′-Dichlorodiphenyl Disulfide in Six Organic Solvents between (303.15 and 333.15) K [J].
Wang, Yana ;
Jia, Yinxia ;
Qian, Chao ;
Tao, Ming ;
Lv, Xuehao ;
Chen, Xinzhi .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2013, 58 (03) :660-662
[9]   Copper-catalyzed aerobic oxidation and cleavage/formation of C-S bond: a novel synthesis of aryl methyl sulfones from aryl halides and DMSO [J].
Yuan, Gaoqing ;
Zheng, Junhua ;
Gao, Xiaofang ;
Li, Xianwei ;
Huang, Liangbin ;
Chen, Huoji ;
Jiang, Huanfeng .
CHEMICAL COMMUNICATIONS, 2012, 48 (60) :7513-7515