Mechanistic Insight into Transition Metal-Catalyzed Reaction of Enynal/Enynone with Alkenes: Metal-Dependent Reaction Pathway

被引：65

作者：

Zhu, Shifa ^{[1
]}

Huang, Hua ^{[1
]}

Zhang, Zhicai ^{[1
]}

Ma, Tongmei ^{[1
]}

Jiang, Huanfeng ^{[1
]}

机构：

[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 79卷 / 13期

关键词：

LEWIS-ACID; O-QUINODIMETHANES; 4+2 CYCLOADDITION; DERIVATIVES; BENZANNULATION; 2-ALKYNYLBENZALDEHYDES; CYCLIZATION; CASCADE; ALKYNES; O-ALKYNYL(OXO)BENZENES;

D O I：

10.1021/jo500838x

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A systematic study of the transition metal-catalyzed reaction of enynal/enynone with alkenes has been reported. It was found that the reaction has two metal-dependent reaction pathways. One led to the formation of 1,2-DHN, while another led to cyclic-o-QDM.

引用

页码：6113 / 6122

页数：10

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