Synthesis, Crystal Structure and Fluorescent Properties of Dinuclear Zinc Complex

被引：0
|
作者：
Bi, Chenglu [1 ]
Li, Weihua [1 ]
Lu, Hui [1 ]
Zhang, Hui [1 ]
Sun, Jianhua [1 ]
机构：
[1] Jiangsu Univ Technol, Sch Chem & Environm Engn, Jiangsu Key Lab Precious Met Chem, Changzhou 213001, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2014年 / 26卷 / 03期
关键词：
Zinc complex; Crystal structure; Dinuclear; Fluorescence; QUINOLINE; CHEMOSENSOR; FRAMEWORKS; IONS;
D O I：
10.14233/ajchem.2014.15525
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A dinuclear zinc complex [Zn-2(qnal)(2)(CH3COO)(2)] (Hqnal: N-(8'-quinolyl)-2-hydroxy-1-naphthaldimine) was synthesized and characterized by X-ray crystallography. The complex crystallizes in monoclinic system, space group C2/c with a = 40.00(3), b = 7.690(5), c = 27.492(16) angstrom, beta = 120.446(11)degrees, V = 17290(8) angstrom(3), Z = 8. D-c = 1.537 g/cm(3), M-r = 843.48, F(000) = 3456, mu(MoKa) = 1.374 mm(-1), S = 1.033, R = 0.0403 and wR = 0.1049 for 4454 observed reflections (I > 2 sigma(I)). It exhibits a 3D supramolecular architecture constructing by pi-pi stacking interactions between quinolyl and naphthyl rings and shows luminescent property in the yellow region.
引用
收藏
页码：761 / 763
页数：3
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