CdS Hollow Spheres Supported on Graphene Oxide Sheets with Enhanced Photocatalytic Activity

被引:13
作者
Mi, Qian
Hu, Juncheng [1 ]
Luo, Man
Huang, Zhengxi
Li, Jinlin
机构
[1] South Central Univ Nationalities, Key Lab Catalysis & Mat Sci, State Ethn Affairs Commiss, Wuhan 430074, Hubei Province, Peoples R China
基金
中国国家自然科学基金;
关键词
CdS; Hollow Spheres; Graphene Oxide; Photocatalytic Activity; ONE-POT SYNTHESIS; H-2-PRODUCTION ACTIVITY; CHEMICAL-REDUCTION; H-2; EVOLUTION; DEGRADATION; COMPOSITE; GRAPHITE; FILMS; NANOPARTICLES; GAS;
D O I
10.1166/sam.2013.1631
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
CdS hollow spheres supported on graphene oxide sheets were successfully synthesized via a simple template-free, biomolecule-assisted method. The samples were characterized by X-ray diffraction (XRD), Transmision electron microscopy (TEM), Fourier transform infrared spectrum (FT-IR), Ultraviolet visible diffuse reflectance spectroscopy (DRS), Brunauer-Emmett-Teller (BET) and Photoluminescence spectra (PL). The photocatalytic activities of the GO/CdS hollow spheres nanocomposites were evaluated by photodegradation of methylene blue and salicylic acid under visible light irradiation. Compared with pure CdS hollow spheres and degussa P25, the GO/CdS hollow spheres nanocomposites show enhanced photocatalytic activity, which is ascribed to graphene oxide as an excellent electron acceptor and transporter, thus reducing the recombination of charge carriers.
引用
收藏
页码:1649 / 1657
页数:9
相关论文
共 57 条
[1]   Synthesis of CdS and ZnS nanowires using single-source molecular precursors [J].
Barrelet, CJ ;
Wu, Y ;
Bell, DC ;
Lieber, CM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (38) :11498-11499
[2]   Evaluation of solution-processed reduced graphene oxide films as transparent conductors [J].
Becerril, Hdctor A. ;
Mao, Jie ;
Liu, Zunfeng ;
Stoltenberg, Randall M. ;
Bao, Zhenan ;
Chen, Yongsheng .
ACS NANO, 2008, 2 (03) :463-470
[3]   Graphite oxide:: Chemical reduction to graphite and surface modification with primary aliphatic amines and amino acids [J].
Bourlinos, AB ;
Gournis, D ;
Petridis, D ;
Szabó, T ;
Szeri, A ;
Dékány, I .
LANGMUIR, 2003, 19 (15) :6050-6055
[4]   A Facile One-step Method to Produce Graphene-CdS Quantum Dot Nanocomposites as Promising Optoelectronic Materials [J].
Cao, Aoneng ;
Liu, Zhen ;
Chu, Saisai ;
Wu, Minghong ;
Ye, Zhangmei ;
Cai, Zhengwei ;
Chang, Yanli ;
Wang, Shufeng ;
Gong, Qihuang ;
Liu, Yuanfang .
ADVANCED MATERIALS, 2010, 22 (01) :103-+
[5]   Preparation, characterization and visible-light photocatalytic activity of AgI/AgCl/TiO2 [J].
Cao, Jing ;
Xu, Benyan ;
Luo, Bangde ;
Lin, Haili ;
Chen, Shifu .
APPLIED SURFACE SCIENCE, 2011, 257 (16) :7083-7089
[6]   Quantum dots sensitized graphene: In situ growth and application in photoelectrochemical cells [J].
Chang, Haixin ;
Lv, Xiaojun ;
Zhang, Hao ;
Li, Jinghong .
ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (03) :483-487
[7]   Applicability of coumarin for detecting and measuring hydroxyl radicals generated by photoexcitation of TiO2 nanoparticles [J].
Czili, Hajnalka ;
Horvath, Attila .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2008, 81 (3-4) :295-302
[8]   Electronic transport properties of individual chemically reduced graphene oxide sheets [J].
Gomez-Navarro, Cristina ;
Weitz, R. Thomas ;
Bittner, Alexander M. ;
Scolari, Matteo ;
Mews, Alf ;
Burghard, Marko ;
Kern, Klaus .
NANO LETTERS, 2007, 7 (11) :3499-3503
[9]   Photocatalytic H2 evolution under visible light irradiation on CdS/ETS-4 composite [J].
Guan, GQ ;
Kida, T ;
Kusakabe, K ;
Kimura, K ;
Fang, XM ;
Ma, TL ;
Abe, E ;
Yoshida, A .
CHEMICAL PHYSICS LETTERS, 2004, 385 (3-4) :319-322
[10]   Photocatalytic reactivity for O2•- and OH• radical formation in anatase and rutile TiO2 suspension as the effect of H2O2 addition [J].
Hirakawa, Tsutomu ;
Yawata, Kenta ;
Nosaka, Yoshio .
APPLIED CATALYSIS A-GENERAL, 2007, 325 (01) :105-111