Aminocyclopropenium Ions: Synthesis, Properties, and Applications

被引：82
作者：
Bandar, Jeffrey S. [1 ]
Lambert, Tristan H. [1 ]
机构：
[1] Columbia Univ, Dept Chem, New York, NY 10027 USA
来源：
SYNTHESIS-STUTTGART | 2013年 / 45卷 / 18期
关键词：
cyclopropenium ions; aromaticity; cyclopropenimines; ionic liquids; ligands; TRANSITION-METAL-COMPLEXES; CYCLOPROPENYL CATIONS; ELECTRONIC-STRUCTURE; DRIVING-FORCE; DELTIC ACID; PAIR STRAIN; IODIDE-IONS; SYSTEMS; CATALYSIS; LIQUIDS;
D O I：
10.1055/s-0033-1338516
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This review covers the preparation, physical properties, and applications of cyclopropenium ions bearing one, two, or three amino substituents. It provides a description of the most reliable methods to access these unique structures as well as a discussion of the reactivity profiles of the common subtypes. 1Introduction 2Preparation 3Properties 3.1Stability 3.2Redox Behavior 3.3Ion Pair Strain 4Reactions 5Applications 5.1Ionic Liquids 5.2Metal Complexes 5.2.1TDAC -Complexes 5.2.2BDAC sigma-Complexes 5.2.3Cyclopropenimine Ligands 5.2.4BDAC-Phosphorus Ligands 5.3BrOnsted Bases 6Conclusion
引用
收藏
页码：2485 / 2498
页数：14
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