Fundamental design of a continuous biomass gasification process using a supercritical water fluidized bed

被引:151
作者
Matsumura, Y
Minowa, T
机构
[1] Hiroshima Univ, Sch Engn, Hiroshima 7398527, Japan
[2] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058569, Japan
关键词
hydrogen production; supercritical water gasification; fluidized bed reactor; biomass;
D O I
10.1016/j.ijhydene.2003.09.005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel biomass gasification (first stage of hydrogen production from biomass) process using a supercritical water fluidized bed was proposed and the fundamental design of the process was conducted. The flow rate was determined by evaluating the minimum fluidization velocity and terminal velocity of alumina particles enabling fluidization with the thermodynamic properties of supercritical water. Three cases were examined: a bubbling fluidized bed in which water was used mainly as the fluidized medium and biomass were added for gasification, a bubbling fluidized bed fluidized by biomass slurry feed alone, and a fast fluidized bed fluidized by biomass slurry feed alone. According to calculations of the residence time and thermal efficiency assuming heat recovery with a heat exchanger efficiency of 0.75, the bubbling fluidized bed fluidized by biomass slurry alone was appropriate for continuous biomass gasification using a fluidized bed. (C) 2003 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:701 / 707
页数:7
相关论文
共 12 条
[1]   Biomass gasification in supercritical water [J].
Antal, MJ ;
Allen, SG ;
Schulman, D ;
Xu, XD ;
Divilio, RJ .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2000, 39 (11) :4040-4053
[2]   CHEMICAL-PROCESSING IN HIGH-PRESSURE AQUEOUS ENVIRONMENTS .4. CONTINUOUS-FLOW REACTOR PROCESS-DEVELOPMENT EXPERIMENTS FOR ORGANICS DESTRUCTION [J].
ELLIOTT, DC ;
PHELPS, MR ;
SEALOCK, LJ ;
BAKER, EG .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1994, 33 (03) :566-574
[3]  
Kato A, 2003, J JPN I ENERGY, V82, P97, DOI DOI 10.3775/JIE.82.97
[4]  
Kunii D., 1991, FLUIDIZATION ENG
[5]   Aggregative and particulate fluidization - The two extremes of a continuous spectrum [J].
Liu, DJ ;
Kwauk, M ;
Li, HZ .
CHEMICAL ENGINEERING SCIENCE, 1996, 51 (17) :4045-4063
[6]  
MATSUMURA Y, 2002, P 8 M SUP FLUIDS CHE, V2, P707
[7]   Phase changing of garbage from solid to liquid slurry by thermal liquidization [J].
Minowa, T ;
Dote, Y ;
Sawayama, S ;
Yokoyama, S ;
Murakami, M .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1995, 28 (06) :727-731
[8]   Hydrogen production from cellulose in hot compressed water using reduced nickel catalyst: Product distribution at different reaction temperatures [J].
Minowa, T ;
Fang, Z .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1998, 31 (03) :488-491
[9]  
The Japan Society of Mechanical Engineers, 1999, JSME STEAM TABL
[10]   Carbon-catalyzed gasification of organic feedstocks in supercritical water [J].
Xu, XD ;
Matsumura, Y ;
Stenberg, J ;
Antal, MJ .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1996, 35 (08) :2522-2530