Conductivity Studies on Filler Free and Filler Doped PVA-PEO Based Blend Polymer Electrolytes

被引:7
作者
Joge, Prajakta [1 ]
Kanchan, Dinesh K. [1 ]
Sharma, Poonam [1 ]
Gondaliya, Nirali [1 ]
机构
[1] Maharaja Sayajirao Univ Baroda, Fac Sci, Dept Phys, Vadodara 390002, Gujarat, India
来源
CONDENSED MATTER AND MATERIALS PHYSICS | 2013年 / 665卷
关键词
Blends; DSC; Conductivity; Al2O3; filler; ELECTRICAL-PROPERTIES; IONIC-CONDUCTIVITY; PLASTICIZERS;
D O I
10.4028/www.scientific.net/AMR.665.227
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The present study deals with the investigation of conduction behavior of filler free and filler based blend electrolyte system. The polymer blend films consisting of PVA and PEO doped with silver salt and PEG plasticizer, are prepared using solution cast technique. The filler free system is prepared for varying ratios of host polymers (PVA: PEO); whereas the filler based system is prepared with various Al2O3 concentrations in the blend films. The conductivity studies of prepared samples are carried out using impedance spectroscopic analysis. The conductivity for the filler free blend system is found to increase with increasing amount of PEO in all the blend specimens. On the other hand, the filler based system shows the conductivity enhancement upto 6wt% which mitigates with further addition of filler into the electrolytes. The DSC scans are found to support the conductivity results.
引用
收藏
页码:227 / 232
页数:6
相关论文
共 50 条
[41]   Using Pegylated Graphene Oxide to Achieve High Performance Solid Polymer Electrolyte Based on Poly(ethylene oxide)/Polyvinyl Alcohol Blend (PEO/PVA) [J].
Eslami, Behnam ;
Ghasemi, Ismaeil ;
Esfandeh, Masoud .
POLYMERS, 2023, 15 (14)
[42]   NMR and conductivity study of PEO-based composite polymer electrolytes [J].
Bloise, AC ;
Donoso, JP ;
Magon, CJ ;
Rosario, AV ;
Pereira, EC .
ELECTROCHIMICA ACTA, 2003, 48 (14-16) :2239-2246
[43]   Extrusion Processed Polymer Electrolytes based on Poly(ethylene oxide) and Modified Sepiolite Nanofibers: Effect of Composition and Filler Nature on Rheology and Conductivity [J].
Mejia, Alberto ;
Garcia, Nuria ;
Guzman, Julio ;
Tiemblo, Pilar .
ELECTROCHIMICA ACTA, 2014, 137 :526-534
[44]   Chitosan filler effects on the experimental characterization, spectroscopic investigation and thermal studies of PVA/PVP blend films [J].
Abdelrazek, E. M. ;
Elashmawi, I. S. ;
Labeeb, S. .
PHYSICA B-CONDENSED MATTER, 2010, 405 (08) :2021-2027
[45]   Investigations on the enhancement mechanism of inorganic filler on ionic conductivity of PEO-based composite polymer electrolyte: The case of molecular sieves [J].
Xi, Jingyu ;
Tang, Xiaozhen .
ELECTROCHIMICA ACTA, 2006, 51 (22) :4765-4770
[46]   Increase of metallic silver nanoparticles in Chitosan:AgNt based polymer electrolytes incorporated with alumina filler [J].
Aziz, Shujahadeen B. ;
Brza, M. A. ;
Mohamed, Pshko A. ;
Kadir, M. F. Z. ;
Hamsan, M. H. ;
Abdulwahid, Rebar T. ;
Woo, H. J. .
RESULTS IN PHYSICS, 2019, 13
[47]   Ionic conductivity and interfacial properties of polymer electrolytes based on PEO and boroxine ring polymer [J].
Yang, YS ;
Inoue, T ;
Fujinami, T ;
Mehta, MA .
JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 84 (01) :17-21
[48]   Electrochemical and Thermal Properties of PEO-LITFSI based Gel Polymer Electrolytes with the Effect of Plasticizer and Filler for Lithium-sulfur Batteries [J].
Nagajothi, A. J. ;
Kannan, R. ;
Thanikaikarasan, S. ;
Sebastian, P. J. .
JOURNAL OF NEW MATERIALS FOR ELECTROCHEMICAL SYSTEMS, 2018, 21 (01) :29-32
[49]   Characterization of proton conducting polymer blend electrolytes based on PVdF-PVA [J].
Muthuvinayagam, M. ;
Gopinathan, C. .
POLYMER, 2015, 68 :122-130
[50]   Effect of TiO2 nano-filler and EC plasticizer on electrical and thermal properties of poly(ethylene oxide) (PEO) based solid polymer electrolytes [J].
Vignarooban, K. ;
Dissanayake, M. A. K. L. ;
Albinsson, I. ;
Mellander, B. -E. .
SOLID STATE IONICS, 2014, 266 :25-28