Toward Two-Photon Absorbing Dyes with Unusually Potentiated Nonlinear Fluorescence Response

被引：20
作者：
Benitez-Martin, Carlos [1 ,2 ,3 ]
Li, Shiming [1 ]
Dominguez-Alfaro, Antonio [4 ,5 ]
Najera, Francisco [2 ,3 ]
Perez-Inestrosa, Ezequiel [2 ,3 ]
Pischel, Uwe [4 ,5 ]
Andreasson, Joakim [1 ]
机构：
[1] Chalmers Univ Technol, Dept Chem & Chem Engn, Phys Chem, SE-41296 Gothenburg, Sweden
[2] Univ Millaga IBIMA, Dept Quim Organ, E-29071 Malaga, Spain
[3] Ctr Andaluz Nanomed & Biotecnol BIONAND, Parque Tecnol Andalucia, E-29590 Malaga, Spain
[4] Univ Huelva, CIQSO Ctr Res Sustainable Chem, E-21071 Huelva, Spain
[5] Univ Huelva, Dept Chem, E-21071 Huelva, Spain
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2020年 / 142卷 / 35期
基金：
瑞典研究理事会;
关键词：
BLUE PHOTOLUMINESCENCE; STIMULATED-EMISSION; 4-PHOTON EXCITATION; ENERGY-TRANSFER; 3-PHOTON; ABSORPTION; PHOTOCHROMISM; MODULATION; MOLECULES; MEMORIES;
D O I：
10.1021/jacs.0c07377
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The combination of two two-photon-induced processes in a Forster resonance energy transfer (FRET)-operated photochromic fluorene-dithienylethene dyad lays the foundation for the observation of a quartic dependence of the fluorescence signal on the excitation light intensity. While this photophysical behavior is predicted for a four-photon absorbing dye, the herein proposed approach opens the way to use two-photon absorbing dyes, reaching the same performance. Hence, the spatial resolution limit, being a critical parameter for applications in fluorescence imaging or data storage with common two-photon absorbing dyes, is dramatically improved.
引用
收藏
页码：14854 / 14858
页数：5
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