Formic acid microfluidic fuel cell evaluation in different oxidant conditions

被引:44
作者
Dector, A. [1 ]
Esquivel, J. P. [2 ]
Gonzalez, M. J. [2 ]
Guerra-Balcazar, M. [3 ]
Ledesma-Garcia, J. [3 ]
Sabate, N. [2 ]
Arriaga, L. G. [1 ]
机构
[1] Ctr Invest & Desarrollo Tecnol Electroquim, Pedro Escobedo 76703, Queretaro, Mexico
[2] IMB CNM CSIC, Inst Microelect Barcelona, Barcelona 08193, Spain
[3] Univ Autonoma Queretaro, Div Invest & Posgrad, Santiago De Queretaro 76010, Mexico
关键词
Formic acid electrooxidation; Microfluidics fuel cells; Dissolved oxygen; Air; Hydrogen peroxide; FABRICATION; CATALYSTS; PEROXIDE; ALKALINE;
D O I
10.1016/j.electacta.2012.12.134
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
This paper presents the electrochemical evaluation from polarization curves of a microfluidic fuel cell that uses formic acid as fuel and different oxidants (dissolved oxygen, air and hydrogen peroxide), concentrations of fuel and flow rates. The micro-device was constructed by UV-lithography technique and the electrocatalysts consisted in commercial Pd/XC-72 and Pt/C for anode and cathode respectively. The maximum power density achieved was 6.7 mW cm(-2) at 0.5 V using 0.5 M HCOOH and dissolved oxygen at 600 mu Lmin(-1). (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:31 / 35
页数:5
相关论文
共 28 条
[1]  
Castaneda F., 2010, J POWER SOURCES, V12, P864
[2]   Microfluidic fuel cell based on laminar flow [J].
Choban, ER ;
Markoski, LJ ;
Wieckowski, A ;
Kenis, PJA .
JOURNAL OF POWER SOURCES, 2004, 128 (01) :54-60
[3]   Characterization of limiting factors in laminar flow-based membraneless microfuel cells [J].
Choban, ER ;
Waszczuk, P ;
Kenis, PJA .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (07) :A348-A352
[4]   Membraneless laminar flow-based micro fuel cells operating in alkaline, acidic, and acidic/alkaline media [J].
Choban, ER ;
Spendelow, JS ;
Gancs, L ;
Wieckowski, A ;
Kenis, PJA .
ELECTROCHIMICA ACTA, 2005, 50 (27) :5390-5398
[5]   Fabrication and preliminary testing of a planar membraneless microchannel fuel cell [J].
Cohen, JL ;
Westly, DA ;
Pechenik, A ;
Abruña, HD .
JOURNAL OF POWER SOURCES, 2005, 139 (1-2) :96-105
[6]   Performance of Au and AuAg nanoparticles supported on Vulcan in a glucose laminar membraneless microfuel cell [J].
Cuevas-Muniz, F. M. ;
Guerra-Balcazar, M. ;
Castaneda, F. ;
Ledesma-Garcia, J. ;
Arriaga, L. G. .
JOURNAL OF POWER SOURCES, 2011, 196 (14) :5853-5857
[7]   Fuel cells for portable applications [J].
Dyer, CK .
JOURNAL OF POWER SOURCES, 2002, 106 (1-2) :31-34
[8]   Towards a compact SU-8 micro-direct methanol fuel cell [J].
Esquivel, J. P. ;
Senn, T. ;
Hernandez-Fernandez, P. ;
Santander, J. ;
Loergen, M. ;
Rojas, S. ;
Loechel, B. ;
Cane, C. ;
Sabate, N. .
JOURNAL OF POWER SOURCES, 2010, 195 (24) :8110-8115
[9]   Membraneless vanadium redox fuel cell using laminar flow [J].
Ferrigno, R ;
Stroock, AD ;
Clark, TD ;
Mayer, M ;
Whitesides, GM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (44) :12930-12931
[10]   Electricity generation from decomposition of hydrogen peroxide [J].
Hasegawa, S ;
Shimotani, K ;
Kishi, K ;
Watanabe, H .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (02) :A119-A121