Nucleation and crystallization behavior of poly(butylene succinate) induced by its α-cyclodextrin inclusion complex:: Effect of stoichiometry

被引:50
作者
Dong, T [1 ]
Shin, KM [1 ]
Zhu, B [1 ]
Inoue, Y [1 ]
机构
[1] Tokyo Inst Technol, Dept Biomol Engn, Midori Ku, Yokohama, Kanagawa 2268501, Japan
关键词
D O I
10.1021/ma052687j
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The effect of stoichiometry on the nucleation and crystallization behavior of poly(butylene succinate) (PBS) was investigated. The nonisothermal crystallization behavior was observed during DSC cooling scan to estimate the nucleation effects of PBS. The small crystallization peaks of PBS were apparent in the temperature range higher than the crystallization temperature of pure PBS. The DSC and POM results demonstrated that the αCD alone cannot effectively enhance crystallization of PBS, regardless of its crystalline structure.
引用
收藏
页码:2427 / 2428
页数:2
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