Form-stable phase change materials with high phase change enthalpy from the composite of paraffin and cross-linking phase change structure

被引:137
作者
Zhang, Yuang [1 ]
Wang, Lingjuan [1 ]
Tang, Bingtao [1 ]
Lu, Rongwen [1 ]
Zhang, Shufen [1 ]
机构
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
基金
中国国家自然科学基金;
关键词
Phase change composite; Phase change enthalpy; Form stable; THERMAL-ENERGY STORAGE; PCM; CONDUCTIVITY; SYSTEMS; MICROENCAPSULATION; ENHANCEMENT; PERFORMANCE;
D O I
10.1016/j.apenergy.2016.10.021
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Large phase-change latent heat and good shape stability are of critical importance in the practical application of phase-change materials for thermal energy storage. This study focuses on a novel strategy to obtain novel phase-change materials with high phase-change enthalpy and form-stable characteristics from the simple composite of paraffin with cross-linking phase-change structure. The structure, thermal properties, crystalline properties, shape-stabilized properties, and thermal stability of the composite materials were determined and analyzed. The phase transition enthalpy of the material can reach 210.6 J/g at a paraffin weight content of 74%. This result was higher than most of the previously reported form-stable PCMs. The shape of the composite was unchanged even after being placed on a 100 degrees C hot plate. This effect was attributed to the supporting mechanism of cross-linking phase-change structure. (c) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:241 / 246
页数:6
相关论文
共 33 条
[1]   State of the art of thermal storage for demand-side management [J].
Arteconi, A. ;
Hewitt, N. J. ;
Polonara, F. .
APPLIED ENERGY, 2012, 93 :371-389
[2]   Microphase separation behavior on the surfaces of PEG-MDI-PDMS multiblock copolymer coatings [J].
Fang, Hongxia ;
Zhou, Shuxue ;
Wu, Limin .
APPLIED SURFACE SCIENCE, 2006, 253 (05) :2978-2983
[3]   Thermal characteristic reliability of fatty acid binary mixtures as phase change materials (PCMs) for thermal energy storage applications [J].
Fauzi, Hadi ;
Metselaar, Hendrik S. C. ;
Mahlia, T. M. I. ;
Silakhori, Mahyar ;
Ong, Hwai Chyuan .
APPLIED THERMAL ENGINEERING, 2015, 80 :127-131
[4]   Microencapsulation of n-hexadecane phase change material by ethyl cellulose polymer [J].
Feczko, Tivadar ;
Kardos, Andrea F. ;
Nemeth, Bence ;
Trif, Laszlo ;
Gyenis, Janos .
POLYMER BULLETIN, 2014, 71 (12) :3289-3304
[5]   Thermal energy storage: "How previous findings determine current research priorities" [J].
Fernandes, D. ;
Pitie, F. ;
Caceres, G. ;
Baeyens, J. .
ENERGY, 2012, 39 (01) :246-257
[6]   Preparation and exhaustive characterization of paraffin or palmitic acid microcapsules as novel phase change material [J].
Giro-Paloma, J. ;
Konuklu, Y. ;
Fernandez, A. I. .
SOLAR ENERGY, 2015, 112 :300-309
[7]   Anomalous Thermal Conduction Characteristics of Phase Change Composites with Single-Walled Carbon Nanotube Inclusions [J].
Harish, Sivasankaran ;
Ishikawa, Kei ;
Chiashi, Shohei ;
Shiomi, Junichiro ;
Maruyama, Shigeo .
JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (29) :15409-15413
[8]  
Inaba H, 1997, HEAT MASS TRANSFER, V32, P307, DOI 10.1007/s002310050126
[9]   Polyethylene glycol (PEG)/diatomite composite as a novel form-stable phase change material for thermal energy storage [J].
Karaman, Sedat ;
Karaipekli, Ali ;
Sari, Ahmet ;
Bicer, Alper .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2011, 95 (07) :1647-1653
[10]   Thermal properties of phase-change materials based on high-density polyethylene filled with micro-encapsulated paraffin wax for thermal energy storage [J].
Karkri, M. ;
Lachheb, M. ;
Nogellova, Z. ;
Boh, B. ;
Sumiga, B. ;
AlMaadeed, M. A. ;
Fethi, A. ;
Krupa, I. .
ENERGY AND BUILDINGS, 2015, 88 :144-152