Gold(III)-catalyzed Intermolecular Hydroamination of C-(tetra-O-acetyl-β-D-galactopyranosyl)allene

被引：1

作者：

Khamwong, Chaleowsak ^{[1
]}

Kruanetr, Senee ^{[1
]}

Sakee, Uthai ^{[1
]}

机构：

[1] Mahasarakham Univ, Fac Sci, Dept Chem, Ctr Excellence Innovat Chem PERCH CIC, Maha Sarakham 44150, Thailand

来源：

LETTERS IN ORGANIC CHEMISTRY | 2012年 / 9卷 / 09期

关键词：

Allene; amine; galactopyranosyl; gold; hydroamination; INTRAMOLECULAR HYDROAMINATION; CATALYZED ADDITION; VINYLARENES; CYCLIZATION; COMPLEXES; ALKENES;

D O I：

10.2174/157017812803521162

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The intermolecular hydroamination of C-(tetra-O-acetyl-beta-D- galactopyranosyl)allene with a variety of aromatic amines proceeded smoothly in the presence of gold(III) catalyst to afford the corresponding allylic amine in good yields. The reaction can be carried out at room temperature and under extremely mild conditions.

引用

页码：650 / 654

页数：5

共 27 条

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