Crystal Structure, Magnetic and Transport Properties of CeRu1-xNixAl (x=0.5)

被引：5
|
作者：
Janka, Oliver [2 ]
Baumbach, Ryan E. [1 ]
Ronning, Filip [1 ]
Thompson, Joe D. [1 ]
Bauer, Eric D. [1 ]
Kauzlarich, Susan M. [2 ]
机构：
[1] Los Alamos Natl Lab, Los Alamos, NM 87545 USA
[2] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2012年 / 638卷 / 12-13期
基金：
美国国家科学基金会;
关键词：
Rare earths; Intermetallics; Magnetic properties; Electrical resistivity; Single crystals; Crystal structure; FLUX; LA; CE;
D O I：
10.1002/zaac.201200173
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Single crystals of CeRu0.5Ni0.5Al can be obtained from a Ce-Ni melt using elements as starting materials. The presented compound crystallizes in the orthorhombic space group Pnma (no. 62) with a = 700.38(7), b = 416.92(4) and c = 1562.84(16) pm in the LaNiAl structure type. The compound shows an unusual temperature dependence of the magnetic susceptibility for T < 20 K although the cerium cations exhibit no local moment behavior. This feature is also visible in the electrical resistivity.
引用
收藏
页码：1996 / 2000
页数：5
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