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Crystal Structure, Magnetic and Transport Properties of CeRu1-xNixAl (x=0.5)
被引:5
|作者:
Janka, Oliver
[2
]
Baumbach, Ryan E.
[1
]
Ronning, Filip
[1
]
Thompson, Joe D.
[1
]
Bauer, Eric D.
[1
]
Kauzlarich, Susan M.
[2
]
机构:
[1] Los Alamos Natl Lab, Los Alamos, NM 87545 USA
[2] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
来源:
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
|
2012年
/
638卷
/
12-13期
基金:
美国国家科学基金会;
关键词:
Rare earths;
Intermetallics;
Magnetic properties;
Electrical resistivity;
Single crystals;
Crystal structure;
FLUX;
LA;
CE;
D O I:
10.1002/zaac.201200173
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
Single crystals of CeRu0.5Ni0.5Al can be obtained from a Ce-Ni melt using elements as starting materials. The presented compound crystallizes in the orthorhombic space group Pnma (no. 62) with a = 700.38(7), b = 416.92(4) and c = 1562.84(16) pm in the LaNiAl structure type. The compound shows an unusual temperature dependence of the magnetic susceptibility for T < 20 K although the cerium cations exhibit no local moment behavior. This feature is also visible in the electrical resistivity.
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页码:1996 / 2000
页数:5
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