Emission of PCDD/Fs and dioxin-like PCBs from metallurgy industries in S. Korea

被引：62

作者：

Yu, BW ^{[1
]}

Jin, GZ ^{[1
]}

Moon, YH ^{[1
]}

Kim, MK ^{[1
]}

Kyoung, JD ^{[1
]}

Chang, YS ^{[1
]}

机构：

[1] Pohang Univ Sci & Technol, Sch Environm Sci & Engn, Pohang 790784, South Korea

来源：

CHEMOSPHERE | 2006年 / 62卷 / 03期

关键词：

PCDD/Fs; PCBs; emission factors; metallurgy industry; Korea;

D O I：

10.1016/j.chemosphere.2005.04.031

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The metallurgy industry and municipal waste incinerators are considered the main sources of polychlorinated dibenzo-p-dioxin and dibenzofurans (PCDD/Fs) in many countries. This study investigated the emission factors and total emissions of PCDD/Fs and dioxin-like polychlorinated biphenyls (PCBs) emitted from metallurgy industries (including ferrous and nonferrous foundries) in Korea. The toxic equivalency (TEQ) emission factor of PCDD/Fs was the highest for secondary copper production, at 24 451 ng I-TEQ/ton. The total estimated emissions of PCDD/Fs from these sources were 35.259 g I-TEQ/yr, comprising 0.088 g I-TEQ/yr from ferrous foundries, 31.713 g I-TEQ/yr from copper production, 1.716 g I-TEQ/yr from lead production, 0.111 g I-TEQ/yr from zinc production, and 1.631 g I-TEQ/yr from aluminum production. The total estimated annual amounts of dioxin-like PCBs emitted from these sources were 13.260 g WHO-TEQ/yr, comprising 0.014 g WHO-TEQ/yr from ferrous foundries, 12.675 g WHO-TEQ/yr from copper production, 0.170 g WHO-TEQ/yr from lead production, 0.017 g WHO-TEQ/yr from zinc production, and 0.384 g WHO-TEQ/yr from aluminum production. The highest emission factor was found for secondary copper smelting, at 9770 ng WHO-TEQ/ton. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：494 / 501

页数：8

共 18 条

[1]

Armin B., 2000, ENVIRON SCI POLLUT R, V6, P44

[2] The emission inventory of PCDD/PCDF in Taiwan [J].

Chen, CM .

CHEMOSPHERE, 2004, 54 (10) :1413-1420

[3]

CHOEI K, 2001, ORGANOHALOGEN COMPD, V50, P297

[4] De novo synthesis of PCDD/F by thermogravimetry [J].

Conesa, JA ;

Fullana, A ;

Font, R .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2002, 36 (02) :263-269

[5]

*DEP ENV UK, 2002, EV CURR PROJ REL CHE

[6] QUANTITATIVE COMPARISON OF DENOVO AND PRECURSOR FORMATION OF POLYCHLORINATED DIBENZO-P-DIOXINS UNDER SIMULATED MUNICIPAL SOLID-WASTE INCINERATOR POSTCOMBUSTION CONDITIONS [J].

DICKSON, LC ;

LENOIR, D ;

HUTZINGER, O .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1992, 26 (09) :1822-1828

[7]

EVALENA W, 2003, ENVIRON SCI TECHNOL, V37, P1962

[8] The formation and emission of dioxins in large scale thermal processes [J].

Everaert, K ;

Baeyens, J .

CHEMOSPHERE, 2002, 46 (03) :439-448

[9]

KIM DH, 2003, ORGANOHALOGEN COMPD, V63, P9

[10]

KIM SC, 2003, ORGANOHALOGEN COMPD, V63, P77

← 1 2 →