PBAT/organoclay composite filmspart 2: effect of UV aging on permeability, mechanical properties and biodegradation

被引:34
作者
Falcao, Gabriella A. M. [1 ]
Almeida, Tatiara G. [1 ]
Bardi, Marcelo A. G. [1 ]
Carvalho, Laura H. [1 ]
Canedo, Eduardo L. [1 ]
机构
[1] Univ Fed Campina Grande, Dept Mat Engn, BR-58429140 Campina Grande, PB, Brazil
关键词
PBAT; Organoclay; Films; Biodegradability; UV aging; NANOCOMPOSITE FILMS;
D O I
10.1007/s00289-018-2385-z
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Biodegradable alternatives are required in order to minimize the environmental impacts caused by inadequate disposal of plastics, especially fast-discharge plastics such as those used in the packaging. This work studied the permeability, mechanical properties and biodegradability of PBAT/organoclay composite films. The materials were melt-mixed in an internal laboratory mixer, and films containing 1, 3 and 5% of organoclay were prepared in a chill roll extruder. The samples were subjected to UV radiation, and their properties were evaluated before and after accelerated aging. Results show that tensile properties, gas permeability and biodegradation depend on filler content and that oxygen and carbon dioxide permeabilities were affected by UV aging. Although the mechanical properties are negatively affected by filler incorporation, oxygen and carbon dioxide permeabilities decreased and biodegradability increased in the composites, making them an interesting option for use in packaging.
引用
收藏
页码:291 / 301
页数:11
相关论文
共 29 条
  • [1] Almeida TG, 2017, MATER RES-IBERO-AM J, V20, P1503, DOI [10.1590/1980-5373-MR-2016-0577, 10.1590/1980-5373-mr-2016-0577]
  • [2] Bastioli C., 2014, Handbook of Biodegradable Polymers, V2
  • [3] Designing carbohydrate nanoparticles for prolonged efficacy of antimicrobial peptide
    Bi, Lin
    Yang, Lei
    Narsimhan, Ganesan
    Bhunia, Arun K.
    Yao, Yuan
    [J]. JOURNAL OF CONTROLLED RELEASE, 2011, 150 (02) : 150 - 156
  • [4] Biodegradable PHB/Copolyester Blends - Biodegradation in Soil
    Casarin, Suzan A.
    Agnelli, Jose A. M.
    Malmonge, Sonia M.
    Rosario, Francisco
    [J]. POLIMEROS-CIENCIA E TECNOLOGIA, 2013, 23 (01): : 115 - 122
  • [5] Characterization of Nanocomposites of Poly(butylene adipate-co-terephthalate) blending with Organoclay
    Chen, Jung-Hung
    Chen, Chin-Chi
    Yang, Ming-Chien
    [J]. JOURNAL OF POLYMER RESEARCH, 2011, 18 (06) : 2151 - 2159
  • [6] Effect of organo-modified montmorillonite on poly(butylene succinate)/poly(butylene adipate-co-terephthalate) nanocomposites
    Chieng, B. W.
    Ibrahim, N. A.
    Yunus, W. M. Z. Wan
    [J]. EXPRESS POLYMER LETTERS, 2010, 4 (07): : 404 - 414
  • [7] Ebnesajjad S, 2013, PDL HANDB SER, pVII
  • [8] PBAT/organoclay composite films: preparation and properties
    Falco, Gabriella A. M.
    Vitorino, Maria B. C.
    Almeida, Tatiara G.
    Bardi, Marcelo A. G.
    Carvalho, Laura H.
    Canedo, Eduardo L.
    [J]. POLYMER BULLETIN, 2017, 74 (11) : 4423 - 4436
  • [9] Effect of physical aging on sorption and permeation of small molecules in polyimide membranes
    Fu, Ywu-Jang
    Hsiao, Sheng-Wen
    Hu, Chien-Chieh
    Qui, Hsuan-Zhi
    Lee, Kueir-Rarn
    Lai, Juin-Yih
    [J]. DESALINATION, 2008, 234 (1-3) : 58 - 65
  • [10] Application of Poly(hydroxyalkanoate) In Food Packaging: Improvements by Nanotechnology
    Khosravi-Darani, K.
    Bucci, D. Z.
    [J]. CHEMICAL AND BIOCHEMICAL ENGINEERING QUARTERLY, 2015, 29 (02) : 275 - 285